(5,10,15,20-tetrakis(4-(2-(2-hydroxyethoxy)ethoxy)phenyl)porphyrinato)zinc(II) | 928204-98-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (5,10,15,20-tetrakis(4-(2-(2-hydroxyethoxy)ethoxy)phenyl)porphyrinato)zinc(II)
• 英文别名: ZnTEEP
• CAS: 928204-98-2
• 化学式: C₁₂₀H₁₂₀N₈O₂₄Zn₂
• 分子量: 2189.09
• InChiKey: KLLPUOYBUYBWEY-ZLQKLWQVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5,10,15,20-tetrakis(4-(2-(2-hydroxyethoxy)ethoxy)phenyl)porphyrine 、 zinc diacetate 以 甲醇 、 氯仿 为溶剂， 以89%的产率得到(5,10,15,20-tetrakis(4-(2-(2-hydroxyethoxy)ethoxy)phenyl)porphyrinato)zinc(II)
  参考文献：
  名称：

  Synthesis, characterisation and X-ray structure of a novel porphyrin array employing Zn–O and O–H…O bonding motifs

  摘要：

  The preparation and characterisation of the free-base and zinc metallated derivatives of 5,10,15,20-tetrakis(4-(2-(2-hydroxyethoxy)ethoxy)phenyl)porphyrin I is described. The X-ray crystal structure of the Zn(II) adduct 2 dimerises in the solid state via an intermolecular polyether oxygen-Zn(II) interaction (O...Zn = 2.124(4) angstrom). The porphyrin dimers form discrete layers defined by a distance of 5.10 angstrom between the porphyrin planes in adjacent layers. A bilayer sheeting arrangement of the porphyrin macrocyclic units is achieved through cooperative hydrogen bonding of the ethoxyethanol arms to form 11-membered macrocycles containing four hydrogen bonds. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.06.002