carbon monoxide;iron;phosphane | 352020-17-8

• 分子结构分类: 有机化合物
• 英文名称: carbon monoxide;iron;phosphane
• CAS: 352020-17-8
• 化学式: C₄H₃FeO₄P
• 分子量: 201.886
• InChiKey: ILMLFLLRCUGOAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.09
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  carbon monoxide;iron;phosphane 在 正丁基锂 作用下， 以 正己烷 、 甲苯 为溶剂， 以76.4%的产率得到
  参考文献：
  名称：

  Schaefer, H.; Leske, W., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为产物：
  描述：

  tetracarbonyl(tris(trimethylsilyl)phosphine)iron(0) 在 甲醇 作用下， 以 乙二醇二甲醚 为溶剂， 生成 carbon monoxide;iron;phosphane
  参考文献：
  名称：

  Schaefer, H.; Leske, W., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：

文献信息

• Stoichiometry-controlled FeP nanoparticles synthesized from a single source precursor
  作者：Cornelia Hunger、Wilfried-Solo Ojo、Susanne Bauer、Shu Xu、Manfred Zabel、Bruno Chaudret、Lise-Marie Lacroix、Manfred Scheer、Céline Nayral、Fabien Delpech

  DOI：10.1039/c3cc46863a

  日期：——

  Phase-pure FeP nanoparticles (NPs) have been synthesized through low temperature thermolysis of the single source precursor [(CO)4Fe(PH3)]. Examination of the mechanism demonstrates the central role of the labile CO ligands and the weak P–H bonds to yield stoichiometry controlled FeP materials.

  相纯的FeP纳米粒子（NPs）是通过低温热解单源前驱体[(CO)4Fe(PH3)]合成的。机制研究表明，易变的CO配体和弱的P–H键在生成计量比受控的FeP材料中发挥了核心作用。
• Synthesis, Characterization, and Reactivity of the Heterometallic Dinuclear μ-PH₂ and μ-PPhH Complexes FeMn(CO)₈(μ-PH₂) and FeMn(CO)₈(μ-PPhH)
  作者：Adam C. Colson、Kenton H. Whitmire

  DOI：10.1021/om100736m

  日期：2010.10.25

  Deprotonation of Fe(CO)(4)PRH2 and treatment with Mn(CO)(5)Br afforded the dinuclear complexes FeMn(CO)(8)(mu-PRH) (1a, R = H; 1b, R = Ph), which contain the relatively rare mu-PH2 and mu-PPhH functionalities. The heterometallic nature of these complexes was confirmed by mass spectrometry, and the molecular structures of 1a and 1b were determined by X-ray diffraction experiments. Deprotonation of 1b and subsequent addition of Mn(CO)(5)Br or AuPPh3Cl yielded the trinuclear complexes FeMn(CO)(8)[mu-PPh(Mn(CO)(5))] (3a) and FeMn(CO)(8)[mu-PPh(AuPPh3)] (3b), both of which were characterized structurally and spectroscopically. Deprotonation of 1a at room temperature resulted in rapid coupling of the deprotonated product [2a](-) with neutral 1a to form M+[FeMn(CO)8(mu(3)-PH)Mn(CO)(4)(mu-PH2)Fe(CO)(4)](-) (M+[4](-)) (M+ = Li+, Na+, K+), the formation of which was observed using in situ infrared spectroscopy. M+[4](-) was found to decompose upon solvent removal, and the structure of [4](-) was elucidated by examination of spectroscopic data. The H-1 NMR spectrum of [4](-) was characterized by first-order [ABMX] and [AMX] spin systems, and ESI-MS data confirmed that [4](-) was formed by direct coupling of [2a](-) with 1a without concomitant fragmentation or loss of CO ligands. Deprotonation of 1a at lower temperatures slowed the coupling process, allowing for the metalation of the monomeric anion [2a](-) by treatment with AuPPh3Cl, the product of which was found to decompose gradually in solution and rapidly upon concentration.
• De, Rajib Lal; Bhar, Sanjib Kumar, Journal of the Indian Chemical Society, 1995, vol. 72, p. 381 - 383
  作者：De, Rajib Lal、Bhar, Sanjib Kumar

  DOI：——

  日期：——