2,3-Xylylphosphonsaeuredimethylester | 115393-12-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3-Xylylphosphonsaeuredimethylester
• 英文别名: 1-Dimethoxyphosphoryl-2,3-dimethylbenzene
• CAS: 115393-12-9
• 化学式: C₁₀H₁₅O₃P
• 分子量: 214.201
• InChiKey: HBLQOBVPGWUJGW-UHFFFAOYSA-N

物化性质

• 沸点：
  298.7±29.0 °C(predicted)
• 密度：
  1.10±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  邻二甲苯 、 亚磷酸二甲酯 生成 2,3-Xylylphosphonsaeuredimethylester
  参考文献：
  名称：

  KOTTMANN, HARIOLF;SKARZEWSKI, JACEK;EFFENBERGER, FRANZ, SYNTHESIS,(1987) N 9, 797-801

  摘要：

  DOI：

文献信息

• Oxidative Phosphonylierung von Aromaten mit Cerammoniumnitrat
  作者：Hariolf Kottmann、Jacek Skarzewski、Franz Effenberger

  DOI：10.1055/s-1987-28077

  日期：——

  Oxidative Phosphonylation of Aromatics with Ammonium Cerium(IV) Nitrate Arylphosphonates 5 and 6 can be prepared in good yields in a one-step synthesis starting from arenes with tri- or diethylphosphites and cerium ammonium nitrate (CAN) as oxidant. The selectivity of the oxidative phosphonylation is relatively low; the reactive species is a phosphite radical cation.

  使用氨铵硝酸铈（IV）对芳香族化合物进行氧化膦酸化反应，可以将芳基膦酸酯5和6在良好的产率下通过一步合成从芳烃与三乙基或二乙基亚磷酸盐以及作为氧化剂的氨铵硝酸铈（CAN）制备。氧化膦酸化反应的选择性相对较低；反应中的活性物质是亚磷酸盐的自由基阳离子。
• POLYETHYLENE-2,6-NAPHTHALATE COMPOSITION WITH EXCELLENT BLOW MOLDABILITY, AND MOLDED PRODUCT THEREOF
  申请人：Teijin Limited

  公开号：EP3109271A1

  公开（公告）日：2016-12-28

  The object of the present invention is to provide a highly crystalline polyethylene-2,6-naphthalate composition by achieving high molecular weight of PEN, wherein the polyethylene-2,6-naphthalate composition has greatly improved blow moldability and provides molded products having excellent hue, excellent weathering resistance, and additionally excellent transparency. The above-mentioned problems can be solved by a polyethylene-2,6-naphthalate composition comprising a specific phosphoric acid which is a phosphorus compound, cobalt element derived from a cobalt compound, manganese element derived from a manganese compound, and antimony element derived from an antimony compound, wherein the content of each of the elements simultaneously satisfies the following expressions (1) to (4): 10≤Co≤30mmol% 0.50≤P/Mn≤1.28 10≤Sb≤25mmol% 0.60≤IV≤1.50dL/g

  本发明的目的是通过实现 PEN 的高分子量来提供一种高结晶性的聚 2,6-萘二甲酸乙二酯组合物，其中聚 2,6-萘二甲酸乙二酯组合物大大提高了吹塑成型性，并提供具有优异色调、优异耐候性和优异透明度的成型产品。上述问题可以通过一种聚 2,6-萘二甲酸乙二醇酯组合物来解决，该组合物包含特定的磷化合物磷酸、从钴化合物中提取的钴元素、从锰化合物中提取的锰元素和从锑化合物中提取的锑元素，其中每种元素的含量同时满足以下表达式（1）至（4）：10≤Co≤30mmol% 0.50≤P/Mn≤1.28 10≤Sb≤25mmol% 0.60≤IV≤1.50dL/g
• POLYTRIMETHYLENE TEREPHTHALATE COMPOSITION, POLYESTER FIBERS, AND METHOD FOR PRODUCING SAME
  申请人：Teijin Limited

  公开号：EP3249012A1

  公开（公告）日：2017-11-29

  A polytrimethylene terephthalate composition including a polyester having a trimethylene terephthalate unit as a main repeating unit, which satisfies all the following requirements : (a) the intrinsic viscosity is 0.50 to 1.60 dL/g; (b) titanium dioxide whose weight distribution of particles having a particle size of more than 1.0 µm is 5.0% by weight or less is contained in an amount of 0.05 to 3.0% by weight; (c) the crystallization exothermic peak top temperature is 165°C or more; and (d) the half-width of the crystallization exothermic peak is 20°C or less. In addition, the invention further encompasses a method for producing a polytrimethylene terephthalate composition using titanium dioxide that has been subjected to a wet-grinding treatment, and also a fiber obtained from the composition. The invention provides a polytrimethylene terephthalate composition, which stabilizes the process in the production of a fiber having small single-fiber fineness by melt-spinning, and is suitable for obtaining a fiber with reduced fluffing.

  一种聚对苯二甲酸三亚甲基酯组合物，包括一种以对苯二甲酸三亚甲基酯单元为主要重复单元的聚酯，该组合物满足以下所有要求：(a)固有粘度为 0.50 至 1.60 dL/g；(b)二氧化钛的重量分布为粒径大于 1.(c) 结晶放热峰顶温度为 165℃或以上；以及 (d) 结晶放热峰的半宽度为 20℃或以下。此外，本发明还包括一种使用经过湿法研磨处理的二氧化钛生产聚对苯二甲酸三甲酯组合物的方法，以及从该组合物中获得的纤维。本发明提供了一种聚对苯二甲酸三甲酯组合物，该组合物可稳定通过熔融纺丝法生产单纤维细度较小的纤维的工艺，并适用于获得绒毛较少的纤维。
• Polyethylene-2,6-naphthalate composition with excellent blow moldability, and molded product thereof
  申请人：TEIJIN LIMITED

  公开号：US10017629B2

  公开（公告）日：2018-07-10

  The object of the present invention is to provide a highly crystalline polyethylene-2,6-naphthalate composition by achieving high molecular weight of PEN, wherein the polyethylene-2,6-naphthalate composition has greatly improved blow moldability and provides molded products having excellent hue, excellent weathering resistance, and additionally excellent transparency. The above-mentioned problems can be solved by a polyethylene-2,6-naphthalate composition comprising a specific phosphoric acid which is a phosphorus compound, cobalt element derived from a cobalt compound, manganese element derived from a manganese compound, and antimony element derived from an antimony compound, wherein the content of each of the elements simultaneously satisfies the following expressions (1) to (4): 10≤Co≤30 mmol %  (1) 0.50≤P/Mn≤1.28  (2) 10≤Sb≤25 mmol %  (3) 0.60≤IV≤1.50 dL/g  (4).

  本发明的目的是通过实现 PEN 的高分子量来提供一种高结晶性的聚 2,6-萘二甲酸乙二酯组合物，其中聚 2,6-萘二甲酸乙二酯组合物大大提高了吹塑成型性，并提供具有优异色调、优异耐候性和优异透明度的成型产品。上述问题可以通过一种聚 2,6-萘二甲酸乙二醇酯组合物来解决，该组合物包含特定的磷化合物磷酸、从钴化合物中提取的钴元素、从锰化合物中提取的锰元素和从锑化合物中提取的锑元素，其中每种元素的含量同时满足以下表达式（1）至（4）： 10≤Co≤30 mmol % (1) 0.50≤P/Mn≤1.28 (2) 10≤Sb≤25 mmol % (3) 0.60≤IV≤1.50 dL/g (4).
• Polytrimethylene terephthalate composition, polyester fiber, and methods for producing the same
  申请人：Teijin Limited

  公开号：US10550241B2

  公开（公告）日：2020-02-04

  A polytrimethylene terephthalate composition including a polyester having a trimethylene terephthalate unit as a main repeating unit, which satisfies all the following requirements: (a) the intrinsic viscosity is 0.50 to 1.60 dL/g; (b) titanium dioxide whose weight distribution of particles having a particle size of more than 1.0 μm is 5.0% by weight or less is contained in an amount of 0.05 to 3.0% by weight; (c) the crystallization exothermic peak top temperature is 165° C. or more; and (d) the half-width of the crystallization exothermic peak is 20° C. or less. In addition, the invention further encompasses a method for producing a polytrimethylene terephthalate composition using titanium dioxide that has been subjected to a wet-grinding treatment, and also a fiber obtained from the composition. The invention provides a polytrimethylene terephthalate composition, which stabilizes the process in the production of a fiber having small single-fiber fineness by melt-spinning, and is suitable for obtaining a fiber with reduced fluffing.

  一种聚对苯二甲酸三甲酯组合物，包括一种以对苯二甲酸三甲酯单元为主要重复单元的聚酯，该组合物满足以下所有要求：(a) 本征粘度为 0.50 至 1.60 dL/g；(b) 二氧化钛的含量为 0.05 至 3.0%(重量)，其粒径大于 1.0 μm 的颗粒的重量分布为 5.0%(重量)或以下；(c) 结晶放热峰顶温度为 165℃或以上；(d) 结晶放热峰的半宽为 20℃或以下。此外，本发明还包括一种使用经过湿法研磨处理的二氧化钛生产聚对苯二甲酸三甲酯组合物的方法，以及从该组合物中获得的纤维。本发明提供了一种聚对苯二甲酸三甲酯组合物，该组合物可稳定通过熔融纺丝法生产单纤维细度较小的纤维的工艺，并适用于获得蓬松度较低的纤维。