2-piperidinylcyclopenta[2,1-b:3,4-b']dipyridine-5-one | 352201-50-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 2-piperidinylcyclopenta[2,1-b:3,4-b']dipyridine-5-one
• 英文别名: 4-Piperidin-1-yl-3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaen-8-one
• CAS: 352201-50-4
• 化学式: C₁₆H₁₅N₃O
• 分子量: 265.315
• InChiKey: DILWBSQLSFZHSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  46.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tetrakis(actonitrile)copper(I) hexafluorophosphate 、 2-piperidinylcyclopenta[2,1-b:3,4-b']dipyridine-5-one 以 甲醇 、 二氯甲烷 为溶剂， 以72%的产率得到bis-(2-piperidinylcyclopenta[2,1-b:3,4-b']dipyridine-5-one)copper(I) hexafluorophosphate
  参考文献：
  名称：

  Copper(I) complexes of cyclopenta[2,1-b:3,4-b′]dipyridine-5-one and some 2-substituted derivatives

  摘要：

  The preparation of 2-chloro-cyclopenta[2,1-b:3,3-b']dipyridine-5-one and its reactions with various nucleophiles are reported. The resulting 3-substituted 4,5-diazafluorenones form complexes [CuL2](+) with copper(I) that are characterised by spectroscopy and microanalysis. The preparation of bis-(cyclopenta[2,1-b:3,4-b']dipyridine-5-one-2-yl)ether and its complexes [ML](+) (M = Cu, Ag) which are shown to be dimeric, are described. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00385-1