| 209847-08-5

• CAS: 209847-08-5
• 化学式: C₃₄H₂₈Cl₂CoN₂O₂
• 分子量: 626.508
• InChiKey: LIJTULWUOUVPRY-DDVHGCDCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dibenzoinlidene-o-phenylene diamine 、 cobalt(II) chloride 以 乙醇 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Complexes of cobalt(II), nickel(II) and copper(II) with ortho- and para-phenylenediamine derivatives

  摘要：

  Cobalt(II), nickel(II) and copper(II) complexes with BOP-H-2 (dibenzoinlidene-o-phenylenediamine) and BPP-H-2 (dibenzoinlidene-p-phenylenediamine) of general formulae [M(H2L)X-2], [M-2(H2L)(2)X-4], [M(L)] and [M-2(L)(2)] (where M = Co, Ni, Cu; X = Cl or NO3; H2L and L are the neutral and dibasic forms of the ligands) have been prepared by the reaction of the corresponding metal salts with the two ligands in neutral and basic media. The complexes were characterised by elemental analysis, electrical conductance, magnetic susceptibility and spectral measurements. The studies revealed two different actions of the ligands, neutral tetradentate in neutral medium giving hexacoordinated metal atoms with octahedral geometry and dibasic tetradentate in alkaline solution giving tetrahedral and square planar structures. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00400-2