[Sn(n-Bu)2Cl(OH)(1,2,3-benzotriazole)2] | 1267752-65-7

• 英文名称: [Sn(n-Bu)2Cl(OH)(1,2,3-benzotriazole)2]
• 英文别名: [Sn(N-Bu)2Cl(OH)(BtzH)2]
• CAS: 1267752-65-7
• 化学式: C₂₀H₂₉ClN₆OSn
• 分子量: 523.653
• InChiKey: OINZWPZCQZDFRT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  T406石油添加剂 、 二丁基二氯化锡 、 水 以 乙醚 为溶剂， 以89%的产率得到[Sn(n-Bu)2Cl(OH)(1,2,3-benzotriazole)2]
  参考文献：
  名称：

  Synthesis, characterization and behaviour in solution of organotin complexes based on azole ligands. Single crystal X-ray study of dichlorodimethylbis(1,2,3-benzotriazole)tin(IV)

  摘要：

  Nine new organotin complexes, namely [SnR2XY(BtzH)(2)] (1: R=Me, X = Y = Cl, 2: R = Me, X = Y = Br, 3: R = Bu-n, X = Cl, Y = OH; 4: R = Ph, X = Y = Cl; Sa: R=Me, X = Y = NO3; 5b: R = Me, X = Y = ClO4) and [SnR2X2(5-NO(2)indH)(2)] (6: R = Me, X = Cl; 7: R = Bu-n, X = Cl; 8: R = Me, X = 5-NO(2)ind) were obtained by reaction of SnR2X2 with BtzH (1,2,3-benzotriazole) and 5-NO(2)indH (5-nitroindazole). These compounds were characterized by IR. NMR and ESI MS, and 1 is shown by a single crystal X-ray study to comprise mononuclear centrosymmetric molecules, all pairs of ligands being mutually opposed in a quasi-octahedral coordination sphere. Sn-Cl, C, N are 2.5700(5), 2.108(2), 2.357(2)angstrom. A new triclinic (P (1) over bar) polymorph of the binuclear [{(Bu2ClSn)-Bu-t(mu-OH)}(2)], 9 is also described (cf. the earlier monoclinic (P2(1)/c)). The unit cell contents comprise a pair of centrosymmetric dimers: Sn-O are 2.042(4)-2.215(4), Sn-Cl 2.489(2), 2.491(2), Sn-C 2.166(6)-2.203(7) A, O-Sn-O 68.4(2) (x2), and Sn-O-Sn 111.6(2)degrees (x2). (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.10.004