| 134735-01-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 134735-01-6
• 化学式: C₈₄H₉₄N₆O₄Zn
• 分子量: 1317.1
• InChiKey: YLZAWBMTAUYJBL-WVUJOURWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 zinc diacetate 以 四氢呋喃 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Influence of linking alkyl chain length on photoinduced intramolecular electron transfer in bipyridine-linked porphyrin-ruthenium dioxide clusters

  摘要：

  In a series of covalently linked meso-tris(octyloxyphenyl)porphyrin-RuO2 composite clusters, the efficiency of photoinduced intramolecular electron transfer from the porphyrin to the covalently attached RuO2 cluster depends on the length of the alkyl chain (-(CH2)n-, n = 1, 4-7) separating the surfactant-like porphyrin from the bipyridine ligating site. The broadening of the porphyrin Soret band and the observation of two distinct triplet-state lifetimes upon complexation to RuO2 are best interpreted as arising from at least two distinct sets of conformers: (1) a family of folded conformers in which RuO2 is complexed to the porphyrin pi-electron system and (2) a family of more extended (noncomplexed) conformers. The complexed conformers exhibit broadened absorption spectra, decreased fluorescence quantum yields, and diminished triplet-state lifetimes compared to the noncomplexed conformers. Axial ligation of the zinc porphyrin to pyridine reduces intramolecular complexation between the porphyrin pi-electron system and the RuO2 cluster in ZnPB(n)R, resulting in unperturbed (narrow) absorption spectra, diminished fluorescence quenching, and a strong diminution of the relative amplitude of the short-lived porphyrin triplet state. However, even in pyridine, the fluorescence intensities, triplet yields, and singlet-state lifetimes of ZnPB(n)R are strongly decreased relative to the unbound porphyrin, whereas the porphyrin triplet-state lifetime is unaffected, suggesting intramolecular electron transfer as a major decay route of the porphyrin excited singlet state in the noncomplexed conformers.

  DOI：

  10.1021/j100169a023