4-甲基-3,6-二(苯基)哒嗪 | 2242-68-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 中文名称: 4-甲基-3,6-二(苯基)哒嗪
• 英文名称: 3,6-diphenyl-4-methylpyridazine
• 英文别名: 4-methyl-3,6-diphenylpyridazine；4-methyl-3,6-diphenyl-pyridazine；4-Methyl-3,6-diphenyl-pyridazin
• CAS: 2242-68-4
• 化学式: C₁₇H₁₄N₂
• 分子量: 246.312
• InChiKey: TVHQKYDAQSQRKW-UHFFFAOYSA-N

物化性质

• 熔点：
  135 °C
• 沸点：
  453.4±14.0 °C(Predicted)
• 密度：
  1.105±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  4-甲基-3,6-二(苯基)哒嗪 、 N,N-二甲基甲酰胺二乙基缩醛 以58%的产率得到
  参考文献：
  名称：

  BACHMANN M.; NEUNHOEFFER H., LIEBIGS ANN. CHEM., 1979, NO 5, 675-688

  摘要：

  DOI：
• 作为产物：
  描述：

  3,7-diphenyl-5,6-dihydro-4H-[1,2]diazepine 以5%的产率得到
  参考文献：
  名称：

  TSUGE O.; KAMATA K., HETEROCYCLES , 1975, 3, NO 1, 15-18

  摘要：

  DOI：

文献信息

• A simple method for the synthesis of some 1,2-diazocines
  作者：Makhluf J. Haddadin、Bushra J. Agha、M.Samer Salka

  DOI：10.1016/s0040-4039(01)81235-1

  日期：1984.1

  Cyclobutanone reacts with diphenyl-1,2,4,5-tetrazine, in alcoholic base and in diethylamine, to give 3,8-diphenyl-6,7-dihydro-1,2-diazocin-4(5H)-one (5) and 4-diethylamino-3,8-diphenyl-6,7-dihydro-1,2-diazocine (8) respectively. With diethylamine the tetrazine yields 3,6-diphenylpyridazine.

  环丁酮与二苯基-1,2,4,5-四嗪在醇碱和二乙胺中反应，生成3,8-二苯基-6,7-二氢-1,2-重氮素4（5H）-一（5 ）和4-二乙氨基-3,8-二苯基-6,7-二氢-1,2-二重氮（8）。与二乙胺一起，四嗪产生3，6-二苯基哒嗪。
• Organic electroluminescence device
  申请人：UDC Ireland

  公开号：US10454042B2

  公开（公告）日：2019-10-22

  An object of the present invention is to provide an organic electroluminescence device having excellent light emission efficiency and durability, in particular, durability when driving at a high temperature. Provided is an organic electroluminescence device including on a substrate a pair of electrodes, and at least one layer of an organic layer including a light emitting layer containing a light emitting material disposed between the electrodes, wherein the light emitting layer includes at least each one of specific indolocarbazole derivatives and specific condensed ring metal complexes.

  本发明的目的是提供一种有机电致发光器件，该器件具有优异的发光效率和耐用性，特别是在高温驱动时的耐用性。本发明提供了一种有机电致发光器件，包括在基底上的一对电极，以及至少一层有机层，该有机层包括设置在电极之间的包含发光材料的发光层，其中发光层包括特定吲哚咔唑衍生物和特定缩合环金属配合物中的至少一种。
• Hunter, Daniel; Neilson, Douglas G., Journal of the Chemical Society. Perkin transactions I, 1983, # 8, p. 1601 - 1603
  作者：Hunter, Daniel、Neilson, Douglas G.

  DOI：——

  日期：——
• HUNTER, D.;NEILSON, D. G., J. CHEM. SOC. PERKIN TRANS., 1983, N 7, 1601-1603
  作者：HUNTER, D.、NEILSON, D. G.

  DOI：——

  日期：——
• Compound for Use in Organic Electroluminescent Device and Organic Electroluminescent Device
  申请人：Komori Masaki

  公开号：US20090302742A1

  公开（公告）日：2009-12-10

  Disclosed are an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, fully secured of driving stability, and simple in constitution and a compound for use therein. The organic electroluminescent device comprises a light-emitting layer disposed between an anode and a cathode piled one upon another on a substrate and the light-emitting layer contains a phosphorescent dopant and a compound for use in an organic electroluminescent device having two or more indolocarbazole skeletons as a host material. An example of the compound having indolocarbazole skeletons for use in the device is expressed by the following formula.