Sm[PPh2]2(tetrahydrofuran)4 | 166821-06-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Sm[PPh2]2(tetrahydrofuran)4
• CAS: 166821-06-3
• 化学式: C₄₀H₅₂O₄P₂Sm
• 分子量: 809.158
• InChiKey: DTQSIYIGSOHECP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Sm[PPh2]2(tetrahydrofuran)4 以 neat (no solvent) 为溶剂， 生成 Sm[PPh2]2(tetrahydrofuran)1.75
  参考文献：
  名称：

  Divalent Lanthanide Chemistry: Three Synthetic Routes to Samarium(II) and Ytterbium(II) Bis(phosphido) Species Including the Structural Characterization of Yb[PPh2]2(thf)4 and Sm[PPh2]2(N-MeIm)4

  摘要：

  As part of a general investigation of low-valent lanthanide phosphido chemistry, the reactions of LnI(2)(thf)(2), LnI(3)(thf)(3), and Ln[N(SiMe(3))(2)](2)(thf)(2) (Ln = Yb, Sm) with KPPh(2) and Ph(2)PH in tetrahydrofuran have been examined. Two different types of lanthanide(II) phosphido complexes of the general formula Ln[PPh(2)](2)(L)(4) with either thf or N-methylimidazole as donor ligands L are reported. The molecular structures show the hexacoordinate lanthanide atoms in slightly distorted octahedral environments with two phosphido ligands in trans positions and slightly pyramidal environments around the phosphorus atoms.

  DOI：

  10.1021/ic00122a003
• 作为产物：
  描述：

  三氢化钐 、 四苯基二膦 在 HgCl₂ 作用下， 以 四氢呋喃 为溶剂， 以0%的产率得到Sm[PPh2]2(tetrahydrofuran)4
  参考文献：
  名称：

  Divalent Lanthanide Chemistry: Three Synthetic Routes to Samarium(II) and Ytterbium(II) Bis(phosphido) Species Including the Structural Characterization of Yb[PPh2]2(thf)4 and Sm[PPh2]2(N-MeIm)4

  摘要：

  As part of a general investigation of low-valent lanthanide phosphido chemistry, the reactions of LnI(2)(thf)(2), LnI(3)(thf)(3), and Ln[N(SiMe(3))(2)](2)(thf)(2) (Ln = Yb, Sm) with KPPh(2) and Ph(2)PH in tetrahydrofuran have been examined. Two different types of lanthanide(II) phosphido complexes of the general formula Ln[PPh(2)](2)(L)(4) with either thf or N-methylimidazole as donor ligands L are reported. The molecular structures show the hexacoordinate lanthanide atoms in slightly distorted octahedral environments with two phosphido ligands in trans positions and slightly pyramidal environments around the phosphorus atoms.

  DOI：

  10.1021/ic00122a003