[Na][(μ-Bu-t-S)(μ-CO)Fe2(CO)6] | 299190-59-3

• 英文名称: [Na][(μ-Bu-t-S)(μ-CO)Fe2(CO)6]
• CAS: 299190-59-3
• 化学式: C₁₁H₉Fe₂O₇S*Na
• 分子量: 419.938
• InChiKey: JAVFZYSWVCCHJO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Na][(μ-Bu-t-S)(μ-CO)Fe2(CO)6] 、 重氮乙酸甲酯 、 碘甲烷 以 四氢呋喃 为溶剂， 以69%的产率得到(μ-Bu-t-S)[μ-η2-N=NCH(Me)CO2Me]Fe2(CO)6
  参考文献：
  名称：

  Reaction of [(μ-RE)(μ-CO)Fe2(CO)6]− (E=S, Se) with N2CHCO2Me. Synthesis and characterisation of (μ-RE)[μ-η2-NNCH(R′)CO2Me]Fe2(CO)6 and (μ-PhSe)[μ-η1-NNCH(Me)CO2Me]Fe2(CO)6

  摘要：

  Reaction of [M][(mu-RE)(mu-CO)Fe-2(CO)(6)] (E = S, Se; M = Et3NH, Na) with N2CHCO2Me give the intermediate [M][(mu-RE)(mu-N2CHCO2Me)Fe-2(CO)(6)] Action of LI with counterion Et3NH+ yields neutral complexes (mu-RE)(mu-eta(2-)N=NCH2CO2Me)Fe-2(CO)(6) (1, RE=Bu'S; 2, RE=PhS; 3, RE=PhSe). Treatment of II (M=Na) with Mel affords (mu-RE)[mu-eta(2)-N=NCH(Me)CO2Me]Fe-2(CO)(6) (4, RE = Bu'S; 5, RE = PhS). In the case of RE = PhSe, the reaction of II with Mel gives two isomers, (mu-PhSe)[mu-eta 2-N=NCH(Me)CO2Me]Fe-2(CO)(6) (6) and (mu-PhSe)[mu-eta(1)-N=NCH(Me)CO2Me]Fe-2(CO)(6) (7). The structure of complex 7 has been determined by single-crystal X-ray diffraction technique. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00246-1
• 作为产物：
  描述：

  十二羰基三铁 、 2-甲基-2-丙硫醇钠盐 以 四氢呋喃 为溶剂， 生成 [Na][(μ-Bu-t-S)(μ-CO)Fe2(CO)6]
  参考文献：
  名称：

  Reaction of [(μ-RE)(μ-CO)Fe2(CO)6]− (E=S, Se) with N2CHCO2Me. Synthesis and characterisation of (μ-RE)[μ-η2-NNCH(R′)CO2Me]Fe2(CO)6 and (μ-PhSe)[μ-η1-NNCH(Me)CO2Me]Fe2(CO)6

  摘要：

  Reaction of [M][(mu-RE)(mu-CO)Fe-2(CO)(6)] (E = S, Se; M = Et3NH, Na) with N2CHCO2Me give the intermediate [M][(mu-RE)(mu-N2CHCO2Me)Fe-2(CO)(6)] Action of LI with counterion Et3NH+ yields neutral complexes (mu-RE)(mu-eta(2-)N=NCH2CO2Me)Fe-2(CO)(6) (1, RE=Bu'S; 2, RE=PhS; 3, RE=PhSe). Treatment of II (M=Na) with Mel affords (mu-RE)[mu-eta(2)-N=NCH(Me)CO2Me]Fe-2(CO)(6) (4, RE = Bu'S; 5, RE = PhS). In the case of RE = PhSe, the reaction of II with Mel gives two isomers, (mu-PhSe)[mu-eta 2-N=NCH(Me)CO2Me]Fe-2(CO)(6) (6) and (mu-PhSe)[mu-eta(1)-N=NCH(Me)CO2Me]Fe-2(CO)(6) (7). The structure of complex 7 has been determined by single-crystal X-ray diffraction technique. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00246-1