[Mn(N,N-propane-1,3-diylbis(salicylidenaminate))Cl] | 99568-94-2

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [Mn(N,N-propane-1,3-diylbis(salicylidenaminate))Cl]
• 英文别名: Mn(salpn)Cl
• CAS: 99568-94-2
• 化学式: C₁₇H₁₆MnN₂O₂*Cl
• 分子量: 370.717
• InChiKey: KPYXRQGPHKRDDO-RDGKIGCSSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 水杨醛 、 1,3-丙二胺 以 乙醇 为溶剂， 生成 [Mn(N,N-propane-1,3-diylbis(salicylidenaminate))Cl]
  参考文献：
  名称：

  Epoxidation of olefins catalysed by Mn(III)-Schiff base complexes

  摘要：

  Mn(III) complexes of Schiff base ligands have been synthesized by the reaction of MnCl2 . 4H2O in ethanolic solutions with the Schiff bases obtained by the condensation of 1,3-diaminopropane or 1,3-diamino-2-hydroxypropane with salicylaldehyde, 2-hydroxynaphthaldehyde or 2-hydroxyacetophenone. The complexes were characterized by elemental analysis, IR spectral, thermogravimetric, conductance, magnetic susceptibility and FAB mass spectral studies. These complexes have been employed as catalysts for the epoxidation of olefins using iodosylbenzene as an oxidant. The effect of-OH substitution on the Schiff base ligand in the complex on its catalytic activity towards epoxidation has been studied.

  DOI：

  10.1016/0304-5102(92)80111-s
• 作为试剂：
  描述：

  双氧水 在 [Mn(N,N-propane-1,3-diylbis(salicylidenaminate))Cl] 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 水 、 氧气
  参考文献：
  名称：

  单核席夫碱锰(III)配合物催化过氧化氢歧化的动力学和机理：螯合物和氢氧离子对N,N-二甲基甲酰胺中过氧化氢歧化的影响

  摘要：

  [Mn(saltnOCOPh)Cl]·DMF (H2saltnOCOPh: N,N'-(2-benzoyloxypropane-1,3-diyl)bis(salicylideneamine))的制备及单核席夫碱锰( III) 络合物，如[Mn(salen)Cl] (H2salen: N,N'-亚乙基双(salicylideneamine)), [Mn(saltn)Cl] (H2saltn: N,N'-propane-1,3-diylbis(水杨烯胺))、[Mn(saltnOH)Cl] (H2saltnOH: N,N'-(2-hydroxypropane-1,3-diyl)bis(salicylideneamine)) 和 [Mn(saltnOCOPh)Cl] 在 N,N-二甲基甲酰胺中(DMF) 进行了调查。H2O2 歧化为 O2 和 H2O 伴随着 Mn(III) 配合物和 Mn(IV)

  DOI：

  10.1246/bcsj.71.609

文献信息

• Richert, Silvia A.; Tsang, Paul K. S.; Sawyer, Donald T., Inorganic Chemistry, 1988, vol. 27, # 10, p. 1814 - 1818
  作者：Richert, Silvia A.、Tsang, Paul K. S.、Sawyer, Donald T.

  DOI：——

  日期：——
• Effects of chloride ions on electrochemical reactions of manganese(III) complexes
  作者：Megumi Kasuno、Masaki Hayano、Manabu Fujiwara、Takayuki Matsushita

  DOI：10.1016/j.poly.2008.10.073

  日期：2009.2

  Electrochemical reactions of manganese(III) complexes, Mn-III(L)X (L; salen, salpn, 5-NO2-salen or 5-NO2-salpn, X; Cl, Br or NO2) and Mn-III(L')(2)X (L': N-Bu-sal, N-Oct-sal, N-Oct-5-Br-sal or N-Oct-5-NO2-sal, X; Cl or Br), were investigated by voltammetry at a glassy carbon electrode in the absence/presence of Cl- in acetonitrile solution. By the addition of Cl-, oxidation processes of Mn-III(L)X and Mn-III(L')(2)X have been found to be improved from quasi-reversible to reversible, and their oxidation products, [Mn-IV(L)X](+) and [Mn-IV(L')(2)X](+), were stabilized by the combination with Cl- resulting in [Mn-IV(L)Cl-2] and [Mn-IV(L')(2)Cl-2], respectively. On the other hand, the reduction processes of Mn-III(L)X and Mn-III(L')(2)Cl were not so significantly affected by Cl- as those observed for their oxidation. Other types of manganese(III) complexes and iron(III) complex were also investigated. The present Study may clarify the role of Cl- being involved in OEC (oxygen-evolving center) in photosystem II. (C) 2008 Elsevier Ltd. All rights reserved.