tetra-2,3-pyridinoporphyrazine cobalt complex | 24315-77-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: tetra-2,3-pyridinoporphyrazine cobalt complex
• 英文别名: Co(II) tetra{2.3-pyridine}tetraazaporphine；cobalt tetrapyridinoporphyrazine；cobalt(II) tetrapyridinoporphyrazine；CoTAP；Co(tetra-2,3-pyridinoporphyrazine)；Co tetrapyridinoporphyrazine；2,3-PycCo；Cobalt(2+);2,5,11,14,20,23,29,32,37,39-decaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene
• CAS: 24315-77-3
• 化学式: C₂₈H₁₂CoN₁₂
• 分子量: 575.477
• InChiKey: WTBAJKIKQAYOTI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  41
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  128
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  tetra-2,3-pyridinoporphyrazine cobalt complex 在 氯化亚砜 、 lithium tetrachloroaluminate 作用下， 生成 CoTAP*SOCl2
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014
• 作为产物：
  描述：

  吡啶-2,3-二甲腈 、 cobalt(II) chloride 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 戊醇 为溶剂， 以0.75 g的产率得到tetra-2,3-pyridinoporphyrazine cobalt complex
  参考文献：
  名称：

  [EN] METAL COMPLEX OR ADDUCT THEREOF, CATALYST COMPRISING METAL COMPLEX OR ADDUCT THEREOF AND METHOD FOR PRODUCING SAME, LIQUID COMPOSITION OR ELECTRODE CONTAINING CATALYST, AND AIR BATTERY OR FUEL CELL EQUIPPED WITH ELECTRODE
  [FR] COMPLEXE MÉTALLIQUE OU PRODUIT D'ADDITION DE CELUI-CI, CATALYSEUR COMPRENANT UN COMPLEXE MÉTALLIQUE OU SON PRODUIT D'ADDITION ET PROCÉDÉ DE PRODUCTION CORRESPONDANT, COMPOSITION LIQUIDE OU ÉLECTRODE CONTENANT UN CATALYSEUR, ET BATTERIE À AIR OU PILE À COMBUSTIBLE ÉQUIPÉE D'UNE ÉLECTRODE
  [JA] 金属錯体又はその付加体、金属錯体又はその付加体を含む触媒及びその製造方法、触媒を含む液状組成物又は電極、電極を備える空気電池又は燃料電池

  摘要：

  这是一段关于金属配合物或其衍生物具有优良的氧还原催化能力，以及包含该金属配合物或其衍生物的催化剂和其制造方法，包含催化剂的液态组成物或电极，以及带有电极的空气电池或燃料电池的描述。其中式（1）或（2）表示的金属配合物或其衍生物，包含该金属配合物或其衍生物的催化剂和其制造方法，包含催化剂的液态组成物或电极，以及带有电极的空气电池或燃料电池。

  公开号：

  WO2022138636A1
• 作为试剂：
  描述：

  氯化亚砜 在 tetra-2,3-pyridinoporphyrazine cobalt complex LiAlCl₄ 作用下， 以 水 为溶剂， 生成 二氧化硫 、 sulfur
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014

文献信息

• Application of cobalt phthalocyanine as a nanostructured catalyst in the synthesis of biological henna-based compounds
  作者：Mohammad Dashteh、Maliheh Safaiee、Saeed Baghery、Mohammad Ali Zolfigol

  DOI：10.1002/aoc.4690

  日期：2019.4

  The present investigation describes synthesis of a good range of henna‐based compounds in the presence of novel nano cobalt phthalocyanine like molten salt (tetra‐2,3‐pyridiniumporphyrazinato cobalt tribromomethanide) [Co (TPPABr)]CBr3 as an efficient, recyclable and thermally stable heterogeneous catalyst.

  本研究描述了新型纳米酞菁钴的存在等熔融盐（四甲基-2,3- pyridiniumporphyrazinato钴tribromomethanide）[CO（TPPABr）] CBR一个良好的范围的基于指甲花的化合物的合成3作为一种高效，可回收和热稳定的非均相催化剂。
• Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic <i>ortho</i>-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
  作者：Mohammad Dashteh、Mohammad Ali Zolfigol、Ardeshir Khazaei、Saeed Baghery、Meysam Yarie、Sajjad Makhdoomi、Maliheh Safaiee

  DOI：10.1039/d0ra02172e

  日期：——

  ortho-Aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines were synthesized by [Co(TPPASO₃H)]Cl as an efficient pyridiniumporphyrazinato based catalyst.

  "ortho"-氨基腈、环己烯-1,3-二胺和2-氨基-3-氰基吡啶通过[Co(TPPASO3H)]Cl作为高效的吡啶基卟啉催化剂合成。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: SVol.B1, 28, page 60 - 61
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• Backer, M. G. de; Sauvage, F. X.; Vlierberge, B. van, Journal de Chimie Physique et de Physico-Chimie Biologique, 1987, vol. 84, p. 915 - 920
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