bis[4-(11-chloro-3,6,9-trioxaundecyloxy)phenylaminoglyoximato]nickel(II) | 444010-54-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: bis[4-(11-chloro-3,6,9-trioxaundecyloxy)phenylaminoglyoximato]nickel(II)
• CAS: 444010-54-2
• 化学式: C₃₂H₄₆Cl₂N₆NiO₁₂
• 分子量: 836.346
• InChiKey: AZBIXSZWZJMPNJ-GHNPEGHJSA-L

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 4-(11-chloro-3,6,9-trioxaundecyloxy)phenylaminoglyoxime 在 NH₃ 作用下， 以 乙醇 为溶剂， 以80%的产率得到bis[4-(11-chloro-3,6,9-trioxaundecyloxy)phenylaminoglyoximato]nickel(II)
  参考文献：
  名称：

  SYNTHESES AND CHARACTERIZATION OF 4-(11-CHLORO-3,6,9-TRIOXAUNDECYLOXY) PHENYLAMINO-GLYOXIME AND ITS COMPLEXES WITH COPPER(II), NICKEL(II), AND COBALT(II)

  摘要：

  A novel vic-dioxime ligand containing ethyleneoxy groups, 4-(11-chloro-3,6,9-trioxaundecyloxy)phenylaminoglyoxime (LH2) has been prepared from 1-amino-4-(11-chloro-3,6,9-trioxaundecyloxy)benzene and monochloro, anti-glyoxime. Its complexes, Ni(LH)(2), Cu(LH)(2) and Co(LH)(2), have been synthesized. The analytical data show that the metal to ligand ratio in the complexes is 1:2. The complexes are formed by coordination of N,N atoms of the ligand. The structures of the oxime ligand (LH2) and its complexes were elucidated by H-1 NMR, IR, UV.-Visible and elemental analyses techniques.

  DOI：

  10.1081/sim-120003801