2-{[2-(2-Hydroxy-ethylamino)-ethylamino]-methyl}-phenol | 158472-17-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-{[2-(2-Hydroxy-ethylamino)-ethylamino]-methyl}-phenol
• 英文别名: 2-[[2-(2-Hydroxyethylamino)ethylamino]methyl]phenol
• CAS: 158472-17-4
• 化学式: C₁₁H₁₈N₂O₂
• 分子量: 210.276
• InChiKey: RYQRSCQJEYDUBL-UHFFFAOYSA-N

物化性质

• 沸点：
  405.5±30.0 °C(predicted)
• 密度：
  1.134±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  64.5
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-氯甲基吡啶 、 2-{[2-(2-Hydroxy-ethylamino)-ethylamino]-methyl}-phenol 在 sodium hydroxide 作用下， 生成 N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethylethylenodiamine
  参考文献：
  名称：

  Synthesis, characterization and catalytic activity toward dye decolorization by manganese (II) mononuclear complexes

  摘要：

  Manganese(II) perchlorate reacts with L1=N,N,N'-tris(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine and L2=N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine in ethanol to form the corresponding complexes [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. Both complexes crystallize in the monoclinic system and space group P 2(1)/n. In [MnL1(H2O)](2+) and [MnL2](+) the manganese(II) ion is heptacoordinated and hexacoordinated, respectively. FTIR, elemental analysis and conductance measurements were all in accordance with the molecular structures of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. The ability of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4 to catalyze the oxidation of the dyes methyl orange and reactive orange 16 was studied in aqueous alkaline solution (carbonate/bicarbonate buffer). Both complexes were active catalysts promoting significant enhancement of dye solution decolorization in comparison to control reactions. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.apcata.2012.12.036
• 作为产物：
  描述：

  水杨醛 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 25.0h， 生成 2-{[2-(2-Hydroxy-ethylamino)-ethylamino]-methyl}-phenol
  参考文献：
  名称：

  Synthesis, characterization and catalytic activity toward dye decolorization by manganese (II) mononuclear complexes

  摘要：

  Manganese(II) perchlorate reacts with L1=N,N,N'-tris(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine and L2=N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine in ethanol to form the corresponding complexes [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. Both complexes crystallize in the monoclinic system and space group P 2(1)/n. In [MnL1(H2O)](2+) and [MnL2](+) the manganese(II) ion is heptacoordinated and hexacoordinated, respectively. FTIR, elemental analysis and conductance measurements were all in accordance with the molecular structures of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. The ability of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4 to catalyze the oxidation of the dyes methyl orange and reactive orange 16 was studied in aqueous alkaline solution (carbonate/bicarbonate buffer). Both complexes were active catalysts promoting significant enhancement of dye solution decolorization in comparison to control reactions. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.apcata.2012.12.036

文献信息

• Neves, Ademir; Romanowski, Stela Maris de Moraes; Vencato, Ivo, Journal of the Chemical Society, Dalton Transactions, 1998, # 4, p. 617 - 622
  作者：Neves, Ademir、Romanowski, Stela Maris de Moraes、Vencato, Ivo、Mangrich, Antonio Salvio

  DOI：——

  日期：——