1,3-diphenyl-2,2,4,4-tetrachloro-2,4-bis(2-imino-3-cyanothiophene)cyclodiphosph(V)azane | 1181660-05-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-diphenyl-2,2,4,4-tetrachloro-2,4-bis(2-imino-3-cyanothiophene)cyclodiphosph(V)azane
• 英文别名: 2-[[2,2,4,4-Tetrachloro-4-[(3-cyanothiophen-2-yl)amino]-1,3-diphenyl-1,3,2lambda5,4lambda5-diazadiphosphetidin-2-yl]amino]thiophene-3-carbonitrile；2-[[2,2,4,4-tetrachloro-4-[(3-cyanothiophen-2-yl)amino]-1,3-diphenyl-1,3,2λ5,4λ5-diazadiphosphetidin-2-yl]amino]thiophene-3-carbonitrile
• CAS: 1181660-05-8
• 化学式: C₂₂H₁₆Cl₄N₆P₂S₂
• 分子量: 632.301
• InChiKey: YUXXSEMMJABMMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.4
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  135
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-氨基噻吩-3-甲腈 、 1,3-diphenyl-2,2,2,4,4,4-hexachloro-1,3-diaza-2,4-diphosphetidine 以 乙腈 为溶剂， 反应 2.0h， 以92%的产率得到1,3-diphenyl-2,2,4,4-tetrachloro-2,4-bis(2-imino-3-cyanothiophene)cyclodiphosph(V)azane
  参考文献：
  名称：

  Studies of Some New Aminocyclodiphosphazane Complexes of Co(II), Ni(II), and Cu(II)

  摘要：

  The ligand aminocyclodiphosph(V)azane derivative (III) and its complexes with Co(II), Ni(II), and Cu(II) ions were prepared and characterized by microanalytical, FTIR, H-1, C-13, and P-31-NMR, UV/Visible, thermogravimetric (TGA) analysis, and magnetic moments. The ligand acts in a tetrahedral manner forming 2:1 metal to ligand ratio. The copper complex is assigned to be tetrahedral while cobalt and nickel complexes were assigned to be octahedral structure.

  DOI：

  10.1080/10426500801964077

文献信息

• Studies of Some New Aminocyclodiphosphazane Complexes of Co(II), Ni(II), and Cu(II)
  作者：A. M. A. Alaghaz

  DOI：10.1080/10426500801964077

  日期：2008.9.15

  The ligand aminocyclodiphosph(V)azane derivative (III) and its complexes with Co(II), Ni(II), and Cu(II) ions were prepared and characterized by microanalytical, FTIR, H-1, C-13, and P-31-NMR, UV/Visible, thermogravimetric (TGA) analysis, and magnetic moments. The ligand acts in a tetrahedral manner forming 2:1 metal to ligand ratio. The copper complex is assigned to be tetrahedral while cobalt and nickel complexes were assigned to be octahedral structure.