N-methyl-N-[(2-methylphenyl)diazenyl]methanamine | 20240-98-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-methyl-N-[(2-methylphenyl)diazenyl]methanamine
• 英文别名: 3,3-dimethyl-1-(2-methylphenyl)triazene
• CAS: 20240-98-6
• 化学式: C₉H₁₃N₃
• 分子量: 163.222
• InChiKey: NHMGJBOPOUILBE-ZHACJKMWSA-N

物化性质

• 沸点：
  280.31°C (rough estimate)
• 密度：
  1.1105 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  2.56
• 重原子数：
  12.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  27.96
• 氢给体数：
  0.0
• 氢受体数：
  2.0

安全信息

• 海关编码：
  2928000090

反应信息

• 作为反应物：
  描述：

  N-methyl-N-[(2-methylphenyl)diazenyl]methanamine 在 正丁基锂 、 水 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以74%的产率得到N,3-二甲基苄胺
  参考文献：
  名称：

  1-芳基-3,3-二烷基三嗪的α-锂化反应以及分子内转化为苄胺和四氢苯并三嗪衍生物。

  摘要：

  DOI：

  10.1002/1521-3773(20020201)41:3<484::aid-anie484>3.0.co;2-w

文献信息

• Composition for film formation, method of film formation, and silica-based film
  申请人：JSR Corporation

  公开号：EP1148105A2

  公开（公告）日：2001-10-24

  A composition for film formation which comprises: (A) a product of hydrolysis and condensation obtained by hydrolyzing and condensing at least one compound selected from the group consisting of (A-1) compounds represented by the following formula (1)         RaSi(OR1)4-a     (1) (A-2) compounds represented by the following formula (2)         Si(OR2)4     (2) and (A-3) compounds represented by the following formula (3)         R3 b (R4O) 3-bSi-(R7)d-Si (OR5)3-cR6 c     (3) (B) at least one member selected from the group consisting of compounds of the metals in Groups IA and IIA of the periodic table; and (C) an organic solvent. A method for film formation using the composition and a silica-based film obtained by the method are also disclosed.

  一种用于成膜的组合物，包括 (A) 通过水解和缩合至少一种选自以下组别的化合物而得到的水解和缩合产物 (A-1) 下式（1）所代表的化合物 RaSi(OR1)4-a (1) (A-2) 下式（2）所代表的化合物 Si(OR2)4 (2) 和 (A-3) 下式(3)所代表的化合物 R3 b (R4O) 3-bSi-(R7)d-Si (OR5)3-cR6 c (3) (B) 至少一个选自元素周期表第 IA 和 IIA 族金属化合物的成员；以及 (C) 有机溶剂。 此外，还公开了使用该组合物形成薄膜的方法以及通过该方法获得的硅基薄膜。
• Formation of benzylamines from triazene compounds via a 1,2-proton shift
  作者：Keiji Nishiwaki、Takashi Ogawa、Kazumi Shigeta、Koichi Takahashi、Keizo Matsuo

  DOI：10.1016/j.tet.2006.04.063

  日期：2006.7

  A new approach to benzylamines using triazene compounds has been developed that is facilitated by the lithiation of aryltriazenes followed by treatment with an electrophile. The regioselectivity of the reaction can be controlled by means of the substituents in the aryl group. The reaction contains the following steps: intramolecular carbon-carbon bond formation involving lithiation of an alkyl group on a 3-nitrogen atom; a 1,2-proton shift; and the subsequent release of nitrogen gas. Through the use of a deuterated triazene, we were able to determine that the reaction proceeds through a 1,2-proton shift. (c) 2006 Elsevier Ltd. All rights reserved.
• US6090414A
  申请人：——

  公开号：US6090414A

  公开（公告）日：2000-07-18