1-(2,4,6-三氯苯基)-3-(5-氨基-2-氯苯胺基)-5-吡唑酮 | 53411-33-9

• 物质功能分类: 染料及颜料 - 染料 - 成色剂
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(2,4,6-三氯苯基)-3-(5-氨基-2-氯苯胺基)-5-吡唑酮
• 中文别名: 成色剂品-264氨基物；品-264氨基物；5-[(5-氨基-2-氯苯基)氨基]-2,4-二氢-2-(2,4,6-三氯苯基)-3H-吡唑-3-酮；3-(5-氨基-2-氯苯胺基)-1-(2,4,6-三氯苯基)-5-吡唑啉酮；1-(2,4,6-三氯苯基)-3-(2-氯-5-氨基苯胺基)-5-吡唑酮
• 英文名称: 3-((5-Amino-2-chlorophenyl)amino)-1-(2,4,6-trichlorophenyl)-1H-pyrazol-5(4H)-one
• 英文别名: 5-(5-amino-2-chlorophenyl)imino-2-(2,4,6-trichlorophenyl)pyrazolidin-3-one
• CAS: 53411-33-9
• 化学式: C₁₅H₁₀Cl₄N₄O
• mdl: MFCD00128804
• 分子量: 404.1
• InChiKey: LDWDFXXBUGPHRO-UHFFFAOYSA-N

物化性质

• 熔点：
  237-238 °C
• 沸点：
  545.4±60.0 °C(Predicted)
• 密度：
  1.68±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.066
• 拓扑面积：
  70.7
• 氢给体数：
  2
• 氢受体数：
  3

安全信息

• 危险品标志：
  Xi
• WGK Germany：
  3
• RTECS号：
  WO9030000
• 海关编码：
  2933199090
• 危险类别：
  6.1(b)
• 安全说明：
  S23,S24/25,S26,S36/37
• 危险类别码：
  R36/37/38,R43
• 包装等级：
  III

制备方法与用途

化学性质 

类白色粉末。

用途 

可用于有机合成，可作感光材料的中间体。

反应信息

• 作为反应物：
  描述：

  1-(2,4,6-三氯苯基)-3-(5-氨基-2-氯苯胺基)-5-吡唑酮 以70%的产率得到
  参考文献：
  名称：

  BIKKINEEV, R. X.;ZOLOTAREV, D. B.;ALPEROVICH, M. A.;ZHURIN, R. B.;BAXMUTO+

  摘要：

  DOI：
• 作为产物：
  描述：

  N-[4-chloro-3-[[5-oxo-1-(2,4,6-trichlorophenyl)pyrazolidin-3-ylidene]amino]phenyl]acetamide 生成 1-(2,4,6-三氯苯基)-3-(5-氨基-2-氯苯胺基)-5-吡唑酮
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Nondiffusible photographic couplers and photographic elements and
  申请人：Eastman Kodak Company

  公开号：US04443536A1

  公开（公告）日：1984-04-17

  Photographic couplers comprising a coupler moiety and a ballast moiety have advantageous properties when the ballast moiety is terminated with a hydroxyphenylsulfonyl or hydroxyphenylsulfinyl group. The couplers are useful in photographic emulsions and element.

  含有偶联体基团和平衡基团的光耦合器，在平衡基团以羟基苯基磺酰基或羟基苯基亚磺酰基结尾时具有优越的性能。这些耦合剂在摄影乳剂和元素中有用。
• Color photographic light-sensitive element
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04297440A1

  公开（公告）日：1981-10-27

  A color photographic light-sensitive element is described comprising a support having thereon a silver halide emulsion layer containing therein a 3-anilino-5-pyrazolone magenta color-forming coupler represented by formula (I) ##STR1## wherein X represents a halogen atom or an alkoxy group; Ar represents an aryl group; R.sub.1 represents hydrogen, a halogen atom, an alkyl group, an alkoxy group or an alkylthio group; Y represents a non-metallic atomic group forming a 5-membered or 6-membered ring together with the ##STR2## group, except that Y does not include a carbonyl group; and Z represents hydrogen or a coupling-off group. The magenta color images obtained after color development processing of the color photographic light-sensitive element have an excellent light-fastness, and the formation of yellow stain in the unexposed areas thereof is prevented.

  本文描述了一种彩色照相感光元件，它包括一个支撑体，其上具有一层银卤化物乳剂层，其中包含一种3-苯基氨基-5-吡唑酮洋红色形成偶联剂，其化学式为（I）：##STR1## 其中，X代表卤素原子或烷氧基；Ar代表芳基；R1代表氢、卤素原子、烷基、烷氧基或烷硫基；Y代表非金属原子团，与##STR2##基共同形成一个5-或6-元环，但Y不包括羰基基团；Z代表氢或偶联断裂基团。彩色照相感光元件在彩色显影处理后获得的洋红色图像具有优异的耐光性，并且防止未曝光区域出现黄色污渍。
• Photographic elements containing ballasted compounds
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0079630A1

  公开（公告）日：1983-05-25

  The present invention relates to compounds of the type comprising a ballasting group which renders said compounds substantially fast to diffusion in hydrophilic colloid media and at least one photographically useful group which is chemically linked to said ballasting group, and to photographic elements containing at least one compound of the type referred to. The ballasting groups in the compounds according to the present invention are derived from mono- or di-esters or -ethers of glycerol. The linkage between ballasting group and photographically useful group can be realized via acid chlorides which are derived from the above-said glycerol derivatives.

  本发明涉及一类化合物，该化合物包含一个压载基团，该基团使所述化合物在亲水胶体介质中的扩散速度大大加快，还涉及至少一个与所述压载基团化学连接的对摄影有用的基团，以及含有至少一种上述化合物的摄影元件。 本发明化合物中的压载基团来自甘油的单酯或二酯或醚。压载基团和摄影用基团之间的连接可以通过酸性氯化物来实现，酸性氯化物来自上述甘油衍生物。
• Photographic element comprising ballasted compounds
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0226664A1

  公开（公告）日：1987-07-01

  The present invention relates to a photographic element comprising in a hydrophilic colloid layer a ballasted compound comprising a ballasting moiety that renders such compound fast to diffusion in said hydrophilic colloid layer and a photographically useful moiety linked to this ballasting moiety, the ballasting moiety corresponding to the general formula: wherein A is hydrogen, C₁-C₂₀ alkyl, or aryl; R is C₁-C₂₀ alkyl; R¹ is hydrogen, hydroxy, sulpho, carboxy, cyano, a halogen atom, trifluoromethyl, hydroxyalkyl, sulphoalkyl, carboxyalkyl, alkyl, alkoxy, alkylthio, acyl, R²CONH- , R²NHCO- , R²NHSO₂ , or R²SO₂N(R³)- , each of R² and R³ being hydrogen, C₁-C₅ alkyl, or aryl and when both present having a same or a different significance. The present invention also relates to compounds comprising such ballasting moiety.

  本发明涉及一种感光元件，该元件在亲水胶体层中包含一种压载化合物，该压载化合物包含使该化合物在所述亲水胶体层中快速扩散的压载分子和与该压载分子相连的对摄影有用的分子，该压载分子对应于通式： 其中 A 是氢、C₁-C₂₀ 烷基或芳基；R 是 C₁-C₂₀ 烷基；R¹ 是氢、羟基、硫代、羧基、氰基、卤素原子、三氟甲基、羟基烷基、硫代烷基、羧基烷基、烷基、烷氧基、烷硫基、酰基、R²CONH- 、R²NHCO- 、R²NHSO₂ 或 R²SO₂N(R³)-，R² 和 R³ 中的每一个都是氢、C₁-C₅烷基或芳基，并且 R² 和 R³ 中的每一个都是氢、C₁-C₅烷基或芳基。 烷基或芳基，当两者同时存在时，具有相同或不同的意义。 本发明还涉及包含此类压载分子的化合物。
• Dye diffusion transfer imaging process for production of retained images
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0260349A1

  公开（公告）日：1988-03-23

  The present invention provides a dye diffusion transfer imaging process for the production of retained images, comprising the steps of: - applying an alkaline aqueous processing composition to an image-wise exposed photographic element that contains in operative association with an alkali-permeable silver halide hydrophilic colloid emulsion layer a redox-activatable compound that initially is immobile in an aqueous alkali-permeable colloid medium and is capable of releasing under alkaline conditions in reduced state a diffusible dye moiety, - providing a silver halide developing agent in said photographic element for being present therein during application of said alkaline aqueous processing composition to cause as a function of development of said silver halide emulsion layer the release of said diffusible dye moiety from said redox-activatable compound upon reduction thereof at the non-silver image areas or the loss of the capacity of said redox-activatable compound of releasing said diffusible dye moiety upon oxidation of said redox-activatable compound at the silver image areas, and - allowing diffusion of said diffusible dye moiety into an extracting liquid or disposable receptor medium and leaving in said photographic element a silver image as well as an UV-absorbing dye image retained congruously with said silver image, said redox-activatable compound comprising at least two dye units together absorbing radiation all over the range between 300 and 450 nm. The present invention also provides a photographic silver halide element comprising such a redox-activatable compound.

  本发明提供了一种用于制作保留图像的染料扩散转移成像工艺，包括以下步骤： - 将碱性水溶液冲洗组合物应用于图像曝光的感光元件，该感光元件含有与透碱卤化银亲水胶体乳剂层有效结合的可氧化还原活化的化合物，该化合物最初在水性透碱胶体介质中不移动，并能在碱性条件下以还原状态释放可扩散的染料分子、 - 在所述感光元件中提供一种卤化银显影剂，以便在使用所述碱性水性冲洗组合物期间存在于其中，从而在所述卤化银乳剂层的显影过程中，使所述氧化还原活化化合物在非银图像区域还原时从所述氧化还原活化化合物中释放所述可扩散染料分子，或使所述氧化还原活化化合物在银图像区域氧化时失去释放所述可扩散染料分子的能力，以及 - 允许所述可扩散染料扩散到提取液或一次性受体介质中，并在所述感光元件中留下银图像以及与所述银图像一致保留的紫外线吸收染料图像、 所述氧化还原活化化合物由至少两个染料单元组成，共同吸收 300 至 450 纳米波长范围内的辐射。本发明还提供了一种包含这种可氧化还原活化化合物的照相卤化银元件。