12-bromododecyl(trihexyl)phosphonium bromide | 1396337-01-1

• 分子结构分类: 有机化合物 - 有机磷化合物 - 四烷基鏻化合物
• 英文名称: 12-bromododecyl(trihexyl)phosphonium bromide
• CAS: 1396337-01-1
• 化学式: Br*C₃₀H₆₃BrP
• 分子量: 614.612
• InChiKey: SSIAGACBBKWQIW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  9.04
• 重原子数：
  33.0
• 可旋转键数：
  27.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  12-bromododecyl(trihexyl)phosphonium bromide 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 反应 144.0h， 生成 bis[12-(trihexylphosphonium)dodecyl]disulphane dibromide
  参考文献：
  名称：

  A phosphonium-type ionic liquid-modified Au electrode: a new platform for entrapping functional molecules on substrate surfaces

  摘要：

  具有二硫键的庞大磷鎓型离子化合物的液态形式被用于有效地分散金基底。该基底将外部化合物纳入离子液体内部形成的空隙中，无论化合物净电荷如何，且不涉及直接键合。

  DOI：

  10.1039/c3cc45251d
• 作为产物：
  描述：

  1,12-二溴十二烷 、 三己基膦 以 甲苯 为溶剂， 反应 70.0h， 以46.3%的产率得到12-bromododecyl(trihexyl)phosphonium bromide
  参考文献：
  名称：

  A phosphonium-type ionic liquid-modified Au electrode: a new platform for entrapping functional molecules on substrate surfaces

  摘要：

  具有二硫键的庞大磷鎓型离子化合物的液态形式被用于有效地分散金基底。该基底将外部化合物纳入离子液体内部形成的空隙中，无论化合物净电荷如何，且不涉及直接键合。

  DOI：

  10.1039/c3cc45251d

文献信息

• CO₂ Reduction Promoted by Imidazole Supported on a Phosphonium-Type Ionic-Liquid-Modified Au Electrode at a Low Overpotential
  作者：Go Iijima、Tatsuya Kitagawa、Akira Katayama、Tomohiko Inomata、Hitoshi Yamaguchi、Kazunori Suzuki、Kazuki Hirata、Yoshimasa Hijikata、Miho Ito、Hideki Masuda

  DOI：10.1021/acscatal.7b03274

  日期：2018.3.2

  The catalytic conversion of CO2 to useful compounds is of great importance from the viewpoint of global warming and development of alternatives to fossil fuels. Electrochemical reduction of CO2 using aromatic N-heterocylic molecules is a promising research area. We describe a high performance electrochemical system for reducing CO2 to formate, methanol, and CO using imidazole incorporated into a phosphonium-type ionic liquid-modified Au electrode, imidazolepIL/Au, at a low onset-potential of -0.32 V versus Ag/AgCl. This represents a significant improvement relative to the onset-potential obtained using a conventional Au electrode (-0.56 V). In the reduction carried out at -0.4 V, formate is mainly generated and methanol and CO are also generated with high efficiency at -0.6 similar to -0.8 V. The generation of methanol is confirmed by experiments using (CO2)-C-13 to generate (CH3OH)-C-13. To understand the reaction behavior of CO2 reduction, we characterized the reactions by conducting potential- and time-dependent in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy (SEIRAS) measurements in D2O. During electrochemical CO2 reduction at -0.8 V, the C-O stretching band for CDOD (or COD) increases and the C=O stretching band for COOD increases at -0.4 V. These findings indicate that CO2 reduction intermediates, CDOD (or COD) and GOOD, are formed, depending on the reduction potential, to convert CO2 to methanol and formate, respectively.