三[4,4,4-三氟-1-(2-噻吩基)-1,3-丁二酮]双(氧化三苯基膦)铕 | 12121-29-8

• 物质功能分类: 医药中间体 - 噻吩类化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三[4,4,4-三氟-1-(2-噻吩基)-1,3-丁二酮]双(氧化三苯基膦)铕
• 英文名称: Eu(TTA)₃(TPPO)₂
• 英文别名: Tris[4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedionato]bis(triphenylphosphine oxide)europium
• CAS: 12121-29-8
• 化学式: C₆₀H₄₂EuF₉O₈P₂S₃
• 分子量: 1372.08
• InChiKey: XYIMJKQGNVTQAC-UHFFFAOYSA-N

物化性质

• 熔点：
  248-251℃

计算性质

• 辛醇/水分配系数(LogP)：
  13.45
• 重原子数：
  83
• 可旋转键数：
  9
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  221
• 氢给体数：
  0
• 氢受体数：
  23

安全信息

• 危险性防范说明：
  P501,P270,P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313,P301+P312+P330
• 危险性描述：
  H302,H315,H319

反应信息

• 作为产物：
  描述：

  europium(III) nitrate hexahydrate 、 2-噻吩甲酰三氟丙酮 、 三苯基氧化膦 在 potassium hydroxide 作用下， 以 水 、 异丙醇 为溶剂， 反应 0.02h， 以73%的产率得到三[4,4,4-三氟-1-(2-噻吩基)-1,3-丁二酮]双(氧化三苯基膦)铕
  参考文献：
  名称：

  Microwave-assisted synthesis of ternary lanthanide(2-thenoyltrifluoroacetone) 3 (triphenylphosphine oxide) 2 complexes

  摘要：

  We report here the fast synthesis by microwave assisted technique of four ternary Ln(TTA)(3)(TPPO)(2) complexes, where Ln = La(III), Eu(III), Tb(III) and Tm(III), TTA = 2-thenoyltrifluoroacetone, and TPPO = triphenylphosphine oxide, which are of interest in luminescence applications. Using this method, the reaction time was decreased to one minute with minimal purification step and the yields are comparable Kto literature values. The target complexes were characterized using H-1,C-13, F-19, P-31 NMR and FTIR spectroscopy, MALDI-TOF mass spectrometry and single -crystal X-ray diffraction. Further, we discuss here a hitherto unreported extensive network of hydrogen bonding interactions present in these complexes. (C) 2017 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2017.04.021

文献信息

• 希土類錯体及びその製造方法、並びにプラスチック成形体
  申请人：株式会社レーザーシステム

  公开号：JP2016166140A

  公开（公告）日：2016-09-15

  【課題】高い耐熱性を有するとともに、長波長の光によっても効率的に発光が可能な希土類錯体及びその製造方法の提供。【解決手段】三価の希土類イオンと、該希土類イオンに配位している配位子と、を有する希土類錯体。式（１）で表されるアニオン基、及び／又は２つ以上のカルボキシラート基を有する酸アニオン配位子と、エノラート基を有するエノラート配位子と、を含む配位子。【選択図】なし

  提供具有高耐热性且能够通过长波长光有效发光的稀土配合物及其制备方法。具有三价稀土离子和与该稀土离子配位的配体的稀土配合物。包括由式（1）表示的阴离子基，以及/或者含有两个或更多的羧基的酸阴离子配体和含有烯醇基的烯醇配体的配体。【选择图】无
• Luminescent properties of complexes Y1−xEux(TTA)3(TPPO)2 in nano-TiO2
  作者：Yuguang Lv、Jingchang Zhang、Weiliang Cao、Yali Fu、Xia Wu

  DOI：10.1016/j.jallcom.2007.07.118

  日期：2008.8

  HTTA (thenoyltrifluoroacetone) and TPPO (trioctylphosphine oxide) complexes with different molar ratios of Eu3+ to Y3+ has been synthesized. Characterization with XRD, IR, UV, elemental analysis and fluorescence spectroscopy has also been carried out. These results showed luminescence of Eu3+ complex was enhanced after doped with Y3+. The organic–inorganic thin film of complexes Y1−xEux(TTA)3(TPPO)2

  摘要 合成了一系列具有不同Eu3+与Y3+摩尔比的HTTA（thenoyltrifluoroacetone）和TPPO（trioctylphosphineoxide）配合物。还进行了XRD、IR、UV、元素分析和荧光光谱的表征。这些结果表明掺杂Y3+后Eu3+配合物的发光增强。制备了纳米 TiO2 中配合物 Y1−xEux(TTA)3(TPPO)2 的有机-无机薄膜，并将纳米 TiO2 用于发光层以改变配合物 Y1−xEux(TTA) 的发光性能)3(TPPO)2。发现配体和金属离子之间存在有效的能量转移过程。
• Syntheses, structures and luminescent properties of Sm (III) and Eu (III) chelates for organic electroluminescent device applications
  作者：Y.J Fu、T.K.S Wong、Y.K Yan、X Hu

  DOI：10.1016/s0925-8388(03)00047-1

  日期：2003.8

  Samarium(III) and europium(III) complexes of the β-diketone ligand (2-thienyl)trifluoroacetylacetone (HTTA) and triphenylphosphine oxide (TPPO) were prepared. The complexes, Sm(TTA) 2 (TPPO) 2 NO 3 ( 1 ), Eu(TTA) 2 (TPPO) 2 NO 3 H 2 O ( 2 ), and Eu(TTA) 3 (TPPO) 2 ( 3 ) were characterized. Single crystal X-ray diffraction molecular structures of complexes 1 and 3 are presented and some of the crystal parameters

  摘要 制备了β-二酮配体（2-噻吩基）三氟乙酰丙酮（HTTA）和三苯基氧化膦（TPPO）的钐（III）和铕（III）配合物。配合物Sm(TTA) 2 (TPPO) 2 NO 3 ( 1 )、Eu(TTA) 2 (TPPO) 2 NO 3 H 2 O ( 2 )和Eu(TTA) 3 (TPPO) 2 ( 3 )分别为表征。给出了配合物 1 和 3 的单晶 X 射线衍射分子结构，配合物 1 的一些晶体参数为：空间群，P 1；a =11.019(4) A, b =11.791(6) A, c =12.535(5) A; α =102.68(3)°，β =102.06(3)°，γ =117.75(3)°；对于络合物 3 ：空间群，P -1，a =11.1946(9) A, b =12.117(2) A, c =23.535(2) A, α =80.047(13)°, β =76.498(7)° ,
• Synthesis and electroluminescent property of ternary complexes Eu(TTA)3M
  作者：Yuguang Lv、Chunxiang Song、Yu Zhang、Jingquan Sha、Cuijuan Liu、Fujun Zhang、Lingxuan Wang

  DOI：10.1016/j.jallcom.2009.11.020

  日期：2010.3

  Three kinds of rare earth ternary complexes of Eu3+ with HTTA and M (M = 5-NO(2)Phen,2,2'-Dipy and TPPO) have been synthesized and characterized using various spectral techniques such as elemental analysis, TGA-DTA, IR, UV and fluorescent. Results show that the complexes of Eu(III) emit strong red luminescence when excited by UV light. The complex Eu(TTA)(3)5NO(2)Phen posses the highest sensitized luminescent efficiency and the longest lifetime in the studied complexes. TG curves indicate that Eu(TTA)(3)5NO(2)Phen is most stable. In device ITO/PVK/Eu(TTA)(3)5NO(2)Phen/Al, Eu3+ may be excited by intramolecular energy transfer from ligands as observed by electroluminescence. The main emitting peak at 614 nm can be attributed to the transition of D-5(0) -> E-7(2) of Eu3+ ion, and this process results in the enhancement of red emission from electroluminescence device. (C) 2009 Elsevier B.V. All rights reserved.
• Characterization of ternary coordination complex of europium with thenoyltrifluoroacetone and triphenylphosphine oxide in situ synthesized in ORMOSIL
  作者：Guodong Qian、Minquan Wang

  DOI：10.1016/s0025-5408(01)00740-1

  日期：2001.11

  By using the in situ synthesis technique, the complex of europium with thenoyltrifluoroacetone. (TTA) and triphenylphosphine oxide (TPPO) was confirmed to synthesize in the transparent monolithic ORMOSIL during heat treatment by IR and photoluminescence spectra. The ORMOSIL doped with the EuTFA-TPPO in situ complex appears to have rather high luminescence intensity and relative intensity ratio of D-5(0)--> F-7(2)/D-5(0)--> F-7(1), i.e., better monochromaticity. The emission intensity of the Eu3+ ions in the ORMOSIL heated at 100 degreesC for 24 h increases by a factor of about 1400 compared to that in the no heat treatment sample. Laser excited high-resolution spectra indicate that the molecular structure of the Eu-TTA-TPPO in situ complex is similar to that of the Eu(TTA)(3)(TPPO)(2) complex. The effective site symmetry of the Eu3+ ion in the Eu-TTA-TPPO in situ complex as well as in the Eu(TTA)(3)(TPPO)(2) complex may be C-1 or C-2 or C-S. It is reasonable to suggest that the Bu-TTA-TPPO in situ complex may be Eu(TTA)(3)(TPPO)(2). (C) 2001 Elsevier Science Ltd. All rights reserved.