Zn(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate) | 1269783-20-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Zn(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate)
• CAS: 1269783-20-1
• 化学式: C₁₇H₁₈N₂S₄Zn
• 分子量: 443.997
• InChiKey: DDFRPUITIIDODA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  24.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  sodium N-ethyl-N-phenyldithiocarbamate 、 zinc(II) acetate dihydrate 、 sodium N-methyl-N-phenyldithiocarbamate 以 水 为溶剂， 以78.52%的产率得到Zn(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate)
  参考文献：
  名称：

  Synthesis of hexadecylamine capped nanoparticles using group 12 complexes of N-alkyl-N-phenyl dithiocarbamate as single-source precursors

  摘要：

  Metal complexes of the type (MLL2)-L-1 [M = Zn, Cd, Hg; L-1 = N-methyl-N-phenyldithiocarbamato and L-2 = N-ethyl-N-phenyldithiocarbamato] have been synthesized and characterized by elemental analyses, FT-IR and NMR spectroscopy. The complexes are formulated as four coordinate species with the dithiocarbamates acting as bidentate chelating ligands. The complexes were thermolysed and used as single-source precursors for the synthesis of HDA-capped MS (M = Zn, Cd, Hg) nanoparticles. The HgS nanoparticles show a narrow size distribution from their TEM images, while the CdS nanoparticles gave crystalline particles with a sharp band absorption edge and a narrow PL band. The ZnS nanoparticles gave crystalline particles with a stacking arrangement. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.10.023

文献信息

• Synthesis, characterization and antimicrobial properties of some mixed ligand complexes of Zn(II) dithiocarbamate with different N-donor ligands
  作者：Damian C. Onwudiwe、Yvonne Boitumelo Nthwane、Anthony C. Ekennia、Eric Hosten

  DOI：10.1016/j.ica.2016.03.033

  日期：2016.6

  All the compounds have been characterized by elemental analysis and spectroscopic techniques (IR and NMR). In addition, the crystal structure of [ZnL1L2bpy] complex is also reported. The structure indicates that the two dithiocarbamate ligands are disordered in 0.67:0.33 ratio and alternatively bond as monodentate and bidentate ligands. The bipyridine acts as a bidentate ligand, and gives the structure

  摘要在本研究中，合成了含有不同N-供体配体（吡啶，2,2'-联吡啶和1,10-菲咯啉）的二硫代氨基甲酸锌（II）的加合物。母体二硫代氨基甲酸酯络合物包含N-甲基-N-苯基二硫代氨基甲酸酯（L1）和N-乙基-N-苯基二硫代氨基甲酸酯（L2），加合物表示为[ZnL1L2py]，[ZnL1L2bpy]和[ZnL1L2phen]（其中py ＝吡啶，bpy ＝ 2，2′-联吡啶，和phen ＝ 1，10-菲咯啉。所有化合物均已通过元素分析和光谱技术（IR和NMR）进行了表征。另外，还报道了[ZnL1L2bpy]配合物的晶体结构。结构表明，两个二硫代氨基甲酸酯配体以0.67：0.33的比率无序排列，并且可以作为单齿和双齿配体键合。联吡啶用作双齿配体，并赋予Zn原子周围的结构扭曲的方形金字塔形状。为了评估其抗菌性能，针对6种病原菌菌株和2种真菌生物体筛选了前体复合物和加合物。配合物的抗菌活性依次为[ZnL1L2]>