Ag2[(N,N-diethyl-N'-camphanyl thiourea-S)(N,N-diethyl-N'-camphanyl thiourea-μ-S,O-1H)]2 | 882512-09-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Ag2[(N,N-diethyl-N'-camphanyl thiourea-S)(N,N-diethyl-N'-camphanyl thiourea-μ-S,O-1H)]2
• CAS: 882512-09-6
• 化学式: C₆₀H₉₄Ag₂N₈O₁₂S₄
• 分子量: 1463.45
• InChiKey: FRQKKJZLEPZANZ-YWTKCGAWSA-L

反应信息

• 作为产物：
  描述：

  N,N-diethyl-N'-camphanyl thiourea 、 silver nitrate 在 Co(II)- or Ni(II)- or Cu(II)- or Zn(II) nitrate 、 Cd(II)- or Pb(II) nitrate 、 HOAc/NaOAc 作用下， 以 氯仿 、 水 为溶剂， 生成 Ag2[(N,N-diethyl-N'-camphanyl thiourea-S)(N,N-diethyl-N'-camphanyl thiourea-μ-S,O-1H)]2
  参考文献：
  名称：

  High and selective Ag(I) bulk liquid membrane transport with N,N-diethyl-N′-camphanyl thiourea and structure of the complex

  摘要：

  The novel N,N-diethyl-N'-camphanyl thiourea has been synthesised and characterised by conventional methods. It has been found by means of competitive three-phase transport and competitive two-phase extraction studies to show very high and selective Ag(I) transport and extraction in the presence of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) using the PH gradient method. A crystal structure suggests that a complex Ag-2[(HL-S)(L-mu-S,O)](2) exists, where both monodentate and bidentate modes of coordination are involved. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.10.008