4',4''-bis(2-carboxybenzoyl)diphenyl sulfone | 32568-84-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4',4''-bis(2-carboxybenzoyl)diphenyl sulfone
• CAS: 32568-84-6
• 化学式: C₂₈H₁₈O₈S
• 分子量: 514.512
• InChiKey: ODFVXMPNOXYQKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.38
• 重原子数：
  37.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  142.88
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  4',4''-bis(2-carboxybenzoyl)diphenyl sulfone 在 氯化亚砜 作用下， 反应 6.0h， 生成 4',4''-bis(2-carboxybenzoyl)diphenyl sulfone pseudodichloride
  参考文献：
  名称：

  4′,4″-bis(2-carboxybenzoyl)diphenyl sulfone pseudodichloride as a new monomer for polyarylenephthalides

  摘要：

  A procedure was developed for oxidation of 4',4aEuro(3)-bis(2-carboxybenzoyl)diphenyl sulfide with per acids (peracetic and trifluoroperacetic). The 4',4aEuro(3)-bis(2-carboxybenzoyl)diphenyl sulfone obtained was converted into pseudodichloride, and three new polyarylenephthalides with regular alternation of the electron-acceptor (diphenyl sulfone) and electron-donor (diphenyl oxide, diphenyl sulfide, terphenyl) fragments were synthesized on its basis. The synthesized monomers can be used in the synthesis of new polyarylenephthalides exhibiting the electronic switching effect.

  DOI：

  10.1134/s1070427215060063
• 作为产物：
  描述：

  4',4''-bis(2-carboxybenzoyl)diphenyl sulfide 在 双氧水 、 溶剂黄146 作用下， 反应 24.0h， 以100%的产率得到4',4''-bis(2-carboxybenzoyl)diphenyl sulfone
  参考文献：
  名称：

  4′,4″-bis(2-carboxybenzoyl)diphenyl sulfone pseudodichloride as a new monomer for polyarylenephthalides

  摘要：

  A procedure was developed for oxidation of 4',4aEuro(3)-bis(2-carboxybenzoyl)diphenyl sulfide with per acids (peracetic and trifluoroperacetic). The 4',4aEuro(3)-bis(2-carboxybenzoyl)diphenyl sulfone obtained was converted into pseudodichloride, and three new polyarylenephthalides with regular alternation of the electron-acceptor (diphenyl sulfone) and electron-donor (diphenyl oxide, diphenyl sulfide, terphenyl) fragments were synthesized on its basis. The synthesized monomers can be used in the synthesis of new polyarylenephthalides exhibiting the electronic switching effect.

  DOI：

  10.1134/s1070427215060063