bis(3-pyridyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)bis(4,4,4-trifluoro-1-furoylbutane-1,3-dionato)copper(II)-dichloromethane (1/1) | 1307800-78-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: bis(3-pyridyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)bis(4,4,4-trifluoro-1-furoylbutane-1,3-dionato)copper(II)-dichloromethane (1/1)
• CAS: 1307800-78-7
• 化学式: CH₂Cl₂*C₄₀H₄₀CuF₆N₆O₁₀
• 分子量: 1027.26
• InChiKey: XPNISYIVCOHIRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(4,4,4-trifluoro-1-furoylbutane-1,3-dionato)copper(II) 、 二氯甲烷 、 2-(pyrid-3-yl)-4,4,5,5-tetramethylimidazolidine-3-oxide-1-oxyl 以 二氯甲烷 为溶剂， 以65%的产率得到bis(3-pyridyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)bis(4,4,4-trifluoro-1-furoylbutane-1,3-dionato)copper(II)-dichloromethane (1/1)
  参考文献：
  名称：

  Synthesis, crystal structure, magnetism and electrochemical properties of two copper(II) furoyltrifluoroacetonate complexes with nitroxide radical

  摘要：

  Two new magnetic copper compounds were obtained using the 4,4,4-trifluoro-1-furoylbutane-1,3-dione (Ftfac) ligand and two nitroxide radicals: 3-pyridyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (NIT-mPy) and 4-hydroxy-2,2,6,6-tetramethylpiperidinyl-N-oxy (Tempol). The complexes with formula [Cu(Ftfac)(2)(NITmPy)(2)] (1) and [Cu(Ftfac)(2)(Tempol)] (2) were structurally characterized by single-crystal X-ray diffraction. In compound 1, the copper ion has a distorted octahedral environment, bound to two NITmpPy ligands through the nitrogen atom of the pyridine ring. In compound 2, the copper ion has a distorted pyramidal environment in which the apical position is occupied by the oxygen atom of the Tempol hydroxyl group. The temperature dependence of the magnetic susceptibility of the two compounds was investigated. It was found that compound 1 presents ferromagnetic interaction (J = 9.1 cm(-1)) among copper(II) ions and NITmPy radicals. As a result of the interconnection between molecular moieties through H-bonds, compound 2 presents an unusual magnetic behavior with alternating ferro-and antiferromagnetic interactions. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.026