| 68191-06-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• CAS: 68191-06-0
• 化学式: C₁₂H₂₈N*C₂₀H₃₇O₇S
• 分子量: 607.937
• InChiKey: DHSGQRNROMKUCR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.25
• 重原子数：
  41.0
• 可旋转键数：
  24.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  109.8
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  sodium docusate 、 四丙基氢氧化铵 在 Amberite IR-120 ion-exchange resin 作用下， 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  [R₄N] [AOT]: A Surfactant Ionic Liquid as a Mild Glycosylation Promoter

  摘要：

  [RN4][AOT] is a versatile surfactant ionic liquid that can be used in combination with N-Iodosuccinimide to promote the room temperature glycosylation of thiophenyl glycoside donors. The conditions are mild, with no requirement for molecular sieves, and are compatible with a wide range of donors and protecting groups. Under these conditions, a different range of disaccharides have been obtained in good to excellent yields and good stereoselectivities. Furthermore, the anomeric outcome of the glycosylation reaction using glycosyl donors with no participating group at C-2 could be tuned by switching the solvent from DCM to MeCN.

  DOI：

  10.1080/07328303.2011.609626