di(3-hydroxy-4,6-dinitro-2-ethoxypyridinato)diaquacopper(II) | 1200447-47-7

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: di(3-hydroxy-4,6-dinitro-2-ethoxypyridinato)diaquacopper(II)
• CAS: 1200447-47-7
• 化学式: C₁₄H₁₆CuN₆O₁₄
• 分子量: 555.859
• InChiKey: REJPGJIKBFQXQK-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 3-hydroxy-4,6-dinitro-2-ethoxypyrine 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 生成 di(3-hydroxy-4,6-dinitro-2-ethoxypyridinato)diaquacopper(II)
  参考文献：
  名称：

  Spectral characteristics and structures of metal complexes with 3-Hydroxy-4,6-dinitro-2-ethoxypyridine: Crystal and molecular structures of di(3-hydroxy-4,6-dinitro-2-ethoxypyridinato)diaquacopper(II)

  摘要：

  Seven complexes of manganese(II), copper(II), cadmium, silver(I), samarium(III), and praseodymium(III) with 3-hydroxy-4,6-dinitro-2-ethoxypyridine (HL) were isolated in the crystalline state and studied by IR and UV spectroscopy. The molecular and crystal structures of di(3-hydroxy-4,6-dinitro-2-ethoxypyridinato) diaquacopper(II) [CuL2(H2O)(2)] were determined. The coordination mode of the organic ligand L- is bidentate chelating through the O(2) oxygen atoms of the hydroxy group and the O(1) atom of the ethoxy group. The coordination polyhedron of the copper atom is a prolate tetragonal bipyramid (4 + 2) with two O(1) atoms in the axial positions (Cu-O(1) 2.413 angstrom) and two O(2) atoms of the two L- ligands and the O(7) atoms of the water molecules in the equatorial plane (Cu-O(2), 1.912 angstrom; Cu-O(7), 1.972 angstrom).

  DOI：

  10.1134/s0036023608100100