[Cu(II)(m-hydroxybenzoate)2(diethylnicotinamide)2] | 1039827-39-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Cu(II)(m-hydroxybenzoate)2(diethylnicotinamide)2]
• 英文别名: [Cu(m-Hba)2(Dena)2]
• CAS: 1039827-39-8
• 化学式: C₃₄H₃₈CuN₄O₈
• 分子量: 694.244
• InChiKey: VVIGKXBAPHZNRA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium 3-hydroxybenzoate 以 水 为溶剂， 生成 [Cu(II)(m-hydroxybenzoate)2(diethylnicotinamide)2]
  参考文献：
  名称：

  Synthesis and characterization of bis(N,N-diethylnicotinamide) m-hydroxybenzoate complexes of Co(II), Ni(H), Cu(II), and Zn(II)

  摘要：

  Four novel mixed-ligand complexes of Co(II), Ni(II), Cu(II), and Zn(II) with m-hydroxybenzoate (m-Hba) and N,N-diethylnicotinamide (Dena) were synthesized and characterized on the basis of elemental analysis, FT-IR spectroscopic study, and solid state UV-Vis spectrophotometric and magnetic-susceptibility data. The thermal behavior of the complexes was studied by combined TG-DTA methods in static air atmosphere, and the mass spectra were recorded. The Co(II), Ni(II), and Zn(II) complexes, except for the Cu(II) complex, contain two molecules of coordinated water, two m-Hba, and two Dena ligands per formula unit. In these complexes, the m-Hba and Dena behave as monodentate ligands via acidic oxygen and nitrogen of the pyridine ring. In the Cu(II) complex, the m-Hba is coordinated as monoanionic bidentate ligand through acidic oxygen and carbonyl oxygen. Dena is bonded with Cu2+ as monodentate ligand by the nitrogen atom of the pyridine ring. The decomposition pathways and the stability of the complexes are interpreted in terms of the proposed structural data. The final decomposition products were found to be the respective metal oxides.

  DOI：

  10.1134/s1070328407060073