[Ag-(bis-methylsulfanyl-methyl)-triisopropyl-silane)2](CF3SO3) | 1091586-72-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [Ag-(bis-methylsulfanyl-methyl)-triisopropyl-silane)2](CF3SO3)
• 英文别名: silver;bis(methylsulfanyl)methyl-tri(propan-2-yl)silane;trifluoromethanesulfonate
• CAS: 1091586-72-9
• 化学式: C₂₅H₅₆AgF₃O₃S₅Si₂
• 分子量: 786.082
• InChiKey: YEVUESKEKTUKOJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  10.56
• 重原子数：
  39
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  167
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  (bis-methylsulfanyl-methyl)-triisopropyl-silane 、 silver trifluoromethanesulfonate 以 甲醇 为溶剂， 以30%的产率得到[Ag-(bis-methylsulfanyl-methyl)-triisopropyl-silane)2](CF3SO3)
  参考文献：
  名称：

  Silyl-Substituted Thioether Ligands and Their Ag(I) Complexes

  摘要：

  Silyl-substituted thioether ligands were prepared that differed in the identity and number of ligating groups attached to silicon and the nature of the alkyl groups on silicon. The ligand syntheses involved deprotonation of a thioether with n-butyllithium followed by reaction with the appropriate chlorosilane. Yields were 45-75% after purification. The majority of the ligands reacted with silver(I) triflate to give stable crystalline products in high yields that could be characterized by single-crystal X-ray crystallography. Depending on the ligand, the structures of the products ranged from discrete complexes to infinite polymeric structures. Apparent argentophilic interactions were commonly observed in the solid-state structures of the complexes (Ag-Ag = 2.909-3.196 angstrom).

  DOI：

  10.1021/ic801580t