| 160791-68-4

• CAS: 160791-68-4
• 化学式: C₂₂H₂₆FeO₄
• 分子量: 410.293
• InChiKey: BXVHEKLNQZAECD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 肼 以 乙醇 、 水 为溶剂， 以74%的产率得到1,1'-bis((3,5-dimethyl-1H-pyrazol-4-yl)methyl)ferrocene
  参考文献：
  名称：

  A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl−(CH₂)₂-Bridged Bis(pyrazole)

  摘要：

  Reactions of ferrocenyl-(CH2)(n)-bridged bis(pyrazoles) with nickelocene afforded inter- and intramolecular dimeric poly(heteronuclear) cyclopentadienylnickel(II) complexes com which a novel toluene-embodied guest-host system was obtained by pi-interaction. The present paper has demonstrated a new class of potentially useful organometallic building blocks for supramolecular assembly and the first example of a pyrazolato ligand exhibiting a charge transfer type pi-interaction.

  DOI：

  10.1021/om800704a
• 作为产物：
  描述：

  1,1'-dihydroxymethylferrocene 、 乙酰丙酮 在 HBF₄ 作用下， 以 水 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl−(CH₂)₂-Bridged Bis(pyrazole)

  摘要：

  Reactions of ferrocenyl-(CH2)(n)-bridged bis(pyrazoles) with nickelocene afforded inter- and intramolecular dimeric poly(heteronuclear) cyclopentadienylnickel(II) complexes com which a novel toluene-embodied guest-host system was obtained by pi-interaction. The present paper has demonstrated a new class of potentially useful organometallic building blocks for supramolecular assembly and the first example of a pyrazolato ligand exhibiting a charge transfer type pi-interaction.

  DOI：

  10.1021/om800704a