2-[6-(1H-benzimidazol-2-yl)pyridin-2-yl]-1H-benzimidazole;nickel(2+);2,4,6-trinitrophenolate | 1264232-72-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2-[6-(1H-benzimidazol-2-yl)pyridin-2-yl]-1H-benzimidazole;nickel(2+);2,4,6-trinitrophenolate
• CAS: 1264232-72-5；588699-72-3
• 化学式: C₅₀H₃₀N₁₆NiO₁₄
• 分子量: 1137.58
• InChiKey: ZABSSAYAVPAIPD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-双(2-苯并咪唑基)吡啶 、 nickel(II) picrate 以 甲醇 为溶剂， 以58%的产率得到2-[6-(1H-benzimidazol-2-yl)pyridin-2-yl]-1H-benzimidazole;nickel(2+);2,4,6-trinitrophenolate
  参考文献：
  名称：

  Synthesis and Characterization of Some Mixed‐Ligand Picrate Complexes of Nickel(II) Involving Heterocyclic Nitrogen Donors

  摘要：

  The present communication describes the synthesis of some mixed-ligand hexacoordinated picrato complexes of nickel(II) of the composition [Ni(PA)(2)(L-L)(2)], where PAH=picric acid and L-L=2-aminobenzothiazole (ABZT), 2-(2'-aminophenyl)benzothiazole (2'-AMPHBZT), 2-(3'-aminophenyl)benzothiazole (3'-AMPHBZT), bipyridine (bpy), o-phenanthroline (phen) or 2,6-bis(benzimidazyl)pyridine (BBZLPY). These complexes were obtained by the interaction of nickel(II) picrate with the corresponding ligands L-L in methanol. The resulting compounds have been characterized by elemental analyses, magnetic, molar conductance and decomposition temperature measurements, electron spin resonance, infrared and electronic spectral studies. All the complexes are thermally stable and behave as non-electrolytes. An octahedral structure has been tentatively proposed for these complexes.

  DOI：

  10.1081/sim-120020332