meso-5-(p-octanoyloxyphenyl)-10,15,20-triphenylporphyrinatonickel(II) | 1173105-75-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: meso-5-(p-octanoyloxyphenyl)-10,15,20-triphenylporphyrinatonickel(II)
• CAS: 1173105-75-3
• 化学式: C₅₂H₄₂N₄NiO₂
• 分子量: 813.621
• InChiKey: DDTFOSBONAZLCO-QLABFGELSA-N

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 meso-5-(p-octanoyloxyphenyl)-10,15,20-triphenylporphyrin 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成 meso-5-(p-octanoyloxyphenyl)-10,15,20-triphenylporphyrinatonickel(II)
  参考文献：
  名称：

  Synthesis and Characterization of Novel Unsymmetrical Porphyrin and its Complexes

  摘要：

  A novel unsymmetrical porphyrin meso-5-(p-octanoyloxyphenyl)-10,15,20-triPhenylporphyrin (OPTPPH2) and relative transition metal complexes (DPTPPM, M = Zn, Fe, Co, Ni, Cu, Mn) were synthesized and characterized by elemental analysis, UV-Vis spectra, mass spectra, H-1 NMR, infrared spectra, Raman spectra, and cyclic voltammetry. In dimethylformamide (DMF), 0.1 mol.L-1 tetrabutylammonium perchlorate (TBAP), these compounds exhibit two or three one-electron reversible redox reactions. Quantum yields of the S-1 center dot S-0 fluorescence are measured at room temperature. These studies will contribute to further choice and application of the liquid crystals.

  DOI：

  10.1080/15533170802255294