trans-diaquabis(2,3-pyridinedicarboxylato-N,O)-cobalt(II) | 56246-28-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: trans-diaquabis(2,3-pyridinedicarboxylato-N,O)-cobalt(II)
• 英文别名: Co(2,3-pyridine-dicarboxylic acid-H)2(H2O)2；3-carboxypyridine-2-carboxylate;cobalt(2+);dihydrate
• CAS: 56246-28-7
• 化学式: C₁₄H₁₂CoN₂O₁₀
• 分子量: 427.25
• InChiKey: ABOPTCPUISMECY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.37
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  183
• 氢给体数：
  4
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  2,3-吡啶二羧酸酐 、 cobalt(II) diacetate tetrahydrate 以 甲醇 为溶剂， 以86%的产率得到trans-diaquabis(2,3-pyridinedicarboxylato-N,O)-cobalt(II)
  参考文献：
  名称：

  Hydrolytic ring opening reactions of anhydrides for first row transition metal dicarboxylate complexes

  摘要：

  Ring opening reactions of 2,3-pyridine dicarboxylic anhydride are studied with hydrated salts of cobalt, nickel and zinc. The hydrated metal salts preferentially hydrolyze 2,3-pyridine dicarboxylic, anhydride rather than causing esterification in methanol medium. Hydrolytic opening of 2,3-pyridine dicarboxylic anhydride by hydrated cobalt(II) acetate and nickel(II) acetate resulted in the corresponding chelate complexes of monodeprotonated 2,3-pyridine dicarboxylic acid. The reaction of copper acetate with pyromellitic dianhydride in the presence of 1,10-phenanthroline gives a dinuclear copper complex whereas a similar reaction with copper(II) chloride gives a mononuclear copper complex. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.06.028

文献信息

• A Hydrated Cobalt(II) Complex of Quinolinic Acid: trans-[Co(C7H4NO4)2(H2O)2]
  作者：N. Okabe、J. Miura、A. Shimosaki

  DOI：10.1107/s0108270196002314

  日期：1996.7.15

  In trans-diaquabis(2,3-pyridinedicarboxylato-N,O)-cobalt(Il), the Co atom lies on an inversion centre and has distorted octahedral coordination defined by two pyridine N atoms, two carboxylato O atoms and two water O atoms. The deprotonated carboxylate group at position 2 and the protonated carboxy group at position 3 are located nearly in the plane of the pyridine ring and are linked by an intramolecular hydrogen bond. The crystal structure is stabilized by intermolecular O-H ... O hydrogen bonds between carboxy and water O atoms.