Diphenyl-((E)-3-phenyl-allyloxy)-silane | 139016-91-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Diphenyl-((E)-3-phenyl-allyloxy)-silane
• CAS: 139016-91-4
• 化学式: C₂₁H₂₀OSi
• 分子量: 316.475
• InChiKey: BZOLIAIRJZIOHM-JLHYYAGUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.25
• 重原子数：
  23.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  Diphenyl-((E)-3-phenyl-allyloxy)-silane 在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以128.8 mg的产率得到3-苯基丙-2-烯-1-醇
  参考文献：
  名称：

  Iron-Catalyzed Hydrosilylation of Aldehydes and Ketones under Solvent-Free Conditions

  摘要：

  Exposure of aldehyde or ketone to 1 mol % BIAN-Fe(C7H8) complex in the presence of diphenyl silane affords the corresponding protected alcohol in excellent yields, under mild reaction conditions. Aldehydes and ketones are reduced cleanly in the presence of a broad range of functional groups under solvent-free conditions.

  DOI：

  10.1021/acs.organomet.5b00630
• 作为产物：
  描述：

  反式肉桂醛 、 二苯基硅烷 在 [bis(2,6-diisopropylaniline)acenaphthene]Fe(η⁶-toluene) 作用下， 以 neat (no solvent) 为溶剂， 生成 Diphenyl-((E)-3-phenyl-allyloxy)-silane
  参考文献：
  名称：

  Iron-Catalyzed Hydrosilylation of Aldehydes and Ketones under Solvent-Free Conditions

  摘要：

  Exposure of aldehyde or ketone to 1 mol % BIAN-Fe(C7H8) complex in the presence of diphenyl silane affords the corresponding protected alcohol in excellent yields, under mild reaction conditions. Aldehydes and ketones are reduced cleanly in the presence of a broad range of functional groups under solvent-free conditions.

  DOI：

  10.1021/acs.organomet.5b00630

文献信息

• Asymmetric catalysis. Production of chiral diols by enantioselective catalytic intramolecular hydrosilation of olefins
  作者：Steven H. Bergens、Pedro Noheda、John Whelan、B. Bosnich

  DOI：10.1021/ja00032a028

  日期：1992.3

  Rhodium(I) chiral diphosphine complexes efficiently and rapidly catalyze the intramolecular hydrosilation of silyl ethers derived from allylic alcohols. The efficiency and rates of intramolecular hydrosilations were determined for a variety of silyl and olefin substituents. The catalysts were found to tolerate a widevariety of silyl substituents, although terminal alkyl olefin substituents were found to

  铑 (I) 手性二膦配合物有效且快速地催化衍生自烯丙醇的甲硅烷基醚的分子内氢化硅烷化。测定了各种甲硅烷基和烯烃取代基的分子内硅氢化的效率和速率。尽管发现末端烷基烯烃取代基会延迟催化作用，但发现这些催化剂可以耐受多种甲硅烷基取代基。发现末端芳基烯烃取代基有效且以合理的速率进行氢化硅烷化
• Gold Nanoparticles and Gold(III) Complexes as General and Selective Hydrosilylation Catalysts
  作者：Avelino Corma、Camino González-Arellano、Marta Iglesias、Félix Sánchez

  DOI：10.1002/anie.200702032

  日期：2007.10.15
• Sequential homogenous catalysis. Catalytic formation of allylic and β-keto silyl ethers from dihydrosilanes and the corresponding alcohols followed by intramolecular hydrosilation
  作者：Xianqi Wang、William W. Ellis、B. Bosnich

  DOI：10.1039/cc9960002561

  日期：——

  The catalyst, [Rh(Ph(2)PCH(2)CH(2)PPh(2))](+) engages in consecutive catalytic sequence where allylic alcohols, beta-keto alcohols and alpha,beta-unsaturated aldehydes in the presence of dihydrosilanes are first converted to the corresponding monohydrosilyl ethers, which are then cyclized.