(Ru(1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)(H2O)2)(2+) | 1219592-37-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: (Ru(1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)(H2O)2)(2+)
• 英文别名: trans-(1,4,8,11-tetra-methyl-1,4,8,11-tetraazacyclotetradecane)O(OH)2 ruthenium(IV) complex；trans-aqua(1,4,8,11-tetramethyl-1,4,8,11-tetraazatetradecane)oxoruthenium(IV)(2+)；trans-[Ru(IV)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)O(OH2)](2+)；trans-[Ru(IV)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(O)(H2O)](2+)；trans-[Ru(IV)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(O)(OH2)](2+)
• CAS: 1219592-37-6；95978-21-5
• 化学式: C₁₄H₃₄N₄O₂Ru
• 分子量: 391.52
• InChiKey: ZXMHAOUMBSARFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium permanganate 、 (Ru(1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)(H2O)2)(2+) 以 水 为溶剂， 生成 锰 、 trans-dioxoruthenium(VI)-(1,4,8,11-tetra-methyl-1,4,8,11-tetraazacyclotetradecane)
  参考文献：
  名称：

  溶剂对 MnO4- 将 RuIVO 氧化为 ORuVIO 的影响。氢原子与氧原子转移

  摘要：

  反式-[RuIV(tmc)(O)(solv)]2+ 氧化为反式-[RuVI(tmc)(O)2]2+ (tmc 为 1,4,8,11-四甲基- 1,4,8,11-四氮杂环十四烷，一种四齿大环叔胺配体；solv = H2O 或 CH3CN) by MnO4- 已在水溶液和乙腈中进行了研究。在水溶液中，速率定律是 -d[MnO4]/dt = kH2O[RuIV][MnO4-] = (kx + (ky)/(Ka)[H+])[RuIV][MnO4-]，kx = (1.49 +/- 0.09) x 101 M-1 s-1 和 ky = (5.72 +/- 0.29) x 104 M-1 s-1 在 298.0 K 和 I = 0.1 M。术语 kx 和 ky 被提议为分别为 MnO4- 和 HMnO4 氧化 RuIV 的速率常数，Ka 是 HMnO4 的酸解离常数。在 [H+] = I = 0.1 M

  DOI：

  10.1021/ja074282f
• 作为产物：
  描述：

  trans-dioxoruthenium(VI)-(1,4,8,11-tetra-methyl-1,4,8,11-tetraazacyclotetradecane) 在 cyclohexenol 作用下， 以 水 为溶剂， 生成 (Ru(1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)(H2O)2)(2+)
  参考文献：
  名称：

  Che, Chi-Ming; Poon, Chung-Kwong, Pure and Applied Chemistry, 1988, vol. 60, p. 1201 - 1204

  摘要：

  DOI：

文献信息

• Novel ruthenium(V) dioxo complexes: synthesis, characterization, and reactivity of trans-[Ru V (tmc)(O)2]ClO4(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)
  作者：Chi-Ming Che、Kwok-Yin Wong

  DOI：10.1039/c39860000229

  日期：——

  trans-[RuV(tmc)(O)2]ClO4(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been generated by electrochemical reduction of trans-[RuVI(tmc)(O)2](ClO4)2 in acetonitrile; it is paramagnetic (µeff.= 1.98 µB) and rapidly disproportionates into trans-[RuVI(tmc)(O)2]2+ and trans-[RuIV(tmc)(O)(OH2)]2+ upon dissolution in aqueous acidic solution.

  反式- [孺V（TMC）（O）2 ] CLO 4（TMC = 1,4,8,11-四甲基-1,4,8,11-四azacyclotetradecane）已经由电化学还原生成的反式- [在乙腈中的Ru VI（TMc）（O）2 ]（ClO 4）2；它是顺磁性的（µ eff。 = 1.98 µ B），并迅速歧化为反式-[Ru VI（TMc）（O）2 ] 2+和反式-[Ru IV（TMc）（O）（OH 2）] 2+溶于酸性水溶液中。
• Kinetics and Mechanism of the Oxidation of Hydroquinones by a <i>trans</i>-Dioxoruthenium(VI) Complex
  作者：William W. Y. Lam、Mendy F. W. Lee、Tai-Chu Lau

  DOI：10.1021/ic051382i

  日期：2006.1.1

  The kinetics of the oxidation of hydroquinone (H(2)Q) and its derivatives (H(2)Q-X) by trans-[Ru(VI)(tmc)(O)(2)](2+) (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) have been studied in aqueous acidic solutions and in acetonitrile. In H(2)O, the oxidation of H(2)Q has the following stoichiometry: trans-[Ru(VI)(tmc)(O)(2)](2+) + H(2)Q --> trans-[Ru(IV)(tmc)(O)(OH(2))](2+) + Q. The reaction

  反-[Ru（VI）（tmc）（O）（2）]（2+）（tmc = 1）对苯二酚（H（2）Q）及其衍生物（H（2）QX）的氧化动力学已经在酸性水溶液和乙腈中研究了（4,8,11-四甲基-1,4,8,11-四氮杂环十四烷）。在H（2）O中，H（2）Q的氧化具有以下化学计量：反式[Ru（VI）（tmc）（O）（2）]（2+）+ H（2）Q->反式-[Ru（IV）（tmc）（O）（OH（2））]（2+）+Q。该反应在Ru（VI）和H（2）Q中均为一阶，并且涉及涉及H（2）Q和HQ（-）的氧化。在pH = 1.79和4.60时，动力学同位素效应分别为k（H（2）O）/ k（D（2）O）= 4.9和1.2。在CH（3）CN中，反应分两个步骤发生，将反式-[Ru（VI）（tmc）（O）（2）]（2+）还原1当量的H（2）Q至反式- [Ru（IV）（tmc）（O）（CH（3）CN）]（2+），然后进一步将另
• Kinetics and mechanism of the oxidation of iodide by trans-dioxoruthenium (VI)
  作者：Tai-Chu Lau、Kent W. C. Lau、Keung Lau

  DOI：10.1039/dt9940003091

  日期：——

  The kinetics of reduction of trans-[Ru(tmc)O2]2+ (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) by iodide has been studied in aqueous acidic solution. The reaction has the following stoichiometry: trans-[Ru(VI)(tmc)O2]2+ + 31- + 2H+ --> trans-[Ru(IV)(tmc)O(OH2)]2+ + l3-. The rate law is -d[Ru(VI)]/dt = (k(a) + k(b)]H+]) [Ru(VI)] [l-] with k(a) = 0.041 +/- 0.013 dm3 mol-1 s-1 and k(b) = 18.5 +/- 0.2 dm6 mol-2 s-2 at 25.0 degrees-C and 0.1 mol dm-3 ionic strength. For k(a) DELTAH(double dagger) = 42.9 +/- 9.4 kJ mol-1 and DELTAS(double dagger) = -131 +/- 40J K-1 mol-1, while for k(b), DELTAH(double dagger) = 36.9 +/- 2.9 kJ mol-1 and DELTAS(double dagger) = -97 +/- 10 J K-1 mol-1. A mechanism involving oxgen-atom transfer from Ru(VI) to iodide is consistent with the data.
• Che, Chi-Ming; Lau, Keung; Lau, Tai-Chu, Journal of the American Chemical Society, 1990, vol. 112, # 13, p. 5176 - 5181
  作者：Che, Chi-Ming、Lau, Keung、Lau, Tai-Chu、Poon, Chung-Kwong

  DOI：——

  日期：——
• Lau, Tai-Chu; Chow, Kwok-Ho; Lau, Kent W. C., Journal of the Chemical Society, Dalton Transactions, 1997, p. 313 - 316
  作者：Lau, Tai-Chu、Chow, Kwok-Ho、Lau, Kent W. C.、Tsang, Wenny Y. K.

  DOI：——

  日期：——