5,7-dibromo-2,3-bis(perfluorohexyl)tieno[3,4-b]pyrazine | 1360073-10-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 5,7-dibromo-2,3-bis(perfluorohexyl)tieno[3,4-b]pyrazine
• 英文别名: 5,7-dibromo-2,3-bis(perfluorohexyl)thieno[3,4-b]pyrazine；2,3-Bis(tridecafluorohexyl)-5,7-dibromothieno[3,4-b]pyrazine；5,7-dibromo-2,3-bis(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)thieno[3,4-b]pyrazine
• CAS: 1360073-10-4
• 化学式: C₁₈Br₂F₂₆N₂S
• 分子量: 930.044
• InChiKey: IVRCARQKOAVMAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  49
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  29

反应信息

• 作为产物：
  描述：

  2,3-bis(perfluorohexyl)-1,2,3,4-tetrahydrothieno[3,4-b]pyrazine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 四氢呋喃 为溶剂， 反应 1.5h， 以91%的产率得到5,7-dibromo-2,3-bis(perfluorohexyl)tieno[3,4-b]pyrazine
  参考文献：
  名称：

  空气稳定的低带隙n型有机高分子半导体参展选择溶解性的全氟溶剂

  摘要：

  一种薄膜晶体管：n型高分子半导体，聚（2,3-双（全氟己基）噻吩并[3,4- b ]吡嗪），通过采用全氟化多相溶剂系统中的Pd催化的缩聚合成。这与在氟化溶剂独家溶解度的n型高分子半导体的第一个例子。含有这种新的n型高分子半导体的有机场效应晶体管的制造中示出（见图）。

  DOI：

  10.1002/anie.201204066

文献信息

• COMPOSITIONS, METHODS, AND SYSTEMS COMPRISING FLUOROUS-SOLUBLE POLYMERS
  申请人：Swager Timothy M.

  公开号：US20120177578A1

  公开（公告）日：2012-07-12

  The present invention generally relates to compositions, methods, and systems comprising polymers that are fluorous-soluble and/or organize at interfaces between a fluorous phase and a non-fluorous phase. In some embodiments, emulsions or films are provided comprising a polymer. The polymers, emulsions, and films can be used in many applications, including for determining, treating, and/or imaging a condition and/or disease in a subject. The polymer may also be incorporated into various optoelectronic device such as photovoltaic cells, organic light-emitting diodes, organic field effect transistors, or the like. In some embodiments, the polymers comprise pi-conjugated backbones, and in some cases, are highly emissive.

  本发明通常涉及包含聚合物的组合物、方法和系统，该聚合物是可以在氟化物相和非氟化物相之间界面上溶解或组织的。在某些实施例中，提供了包含聚合物的乳液或薄膜。这些聚合物、乳液和薄膜可以用于许多应用，包括用于确定、治疗和/或成像受试者的状况和/或疾病。该聚合物也可以被纳入各种光电器件中，如光伏电池、有机发光二极管、有机场效应晶体管等。在某些实施例中，该聚合物包括π-共轭骨架，并且在某些情况下，具有高发光性。
• Compositions, methods, and systems comprising fluorous-soluble polymers
  申请人：Swager Timothy M.

  公开号：US09156938B2

  公开（公告）日：2015-10-13

  The present invention generally relates to compositions, methods, and systems comprising polymers that are fluorous-soluble and/or organize at interfaces between a fluorous phase and a non-fluorous phase. In some embodiments, emulsions or films are provided comprising a polymer. The polymers, emulsions, and films can be used in many applications, including for determining, treating, and/or imaging a condition and/or disease in a subject. The polymer may also be incorporated into various optoelectronic device such as photovoltaic cells, organic light-emitting diodes, organic field effect transistors, or the like. In some embodiments, the polymers comprise pi-conjugated backbones, and in some cases, are highly emissive.

  本发明通常涉及包含能够在氟烃相和非氟烃相之间溶解或组织的聚合物的组合物、方法和系统。在某些实施例中，提供了包含聚合物的乳液或薄膜。这些聚合物、乳液和薄膜可用于许多应用，包括用于确定、治疗和/或成像受试者的状况和/或疾病。聚合物还可以被纳入各种光电器件中，例如光伏电池、有机发光二极管、有机场效应晶体管等。在某些实施例中，这些聚合物包括π-共轭主链，并且在某些情况下具有高发光性。
• US9156938B2
  申请人：——

  公开号：US9156938B2

  公开（公告）日：2015-10-13
• [EN] COMPOSITIONS, METHODS, AND SYSTEMS COMPRISING FLUOROUS-SOLUBLE POLYMERS<br/>[FR] COMPOSITIONS, PROCÉDÉS, ET SYSTÈMES COMPRENANT DES POLYMÈRES SOLUBLES DANS LE FLUOR
  申请人：MASSACHUSETTS INST TECHNOLOGY

  公开号：WO2012024592A2

  公开（公告）日：2012-02-23

  The present invention generally relates to compositions, methods, and systems comprising polymers that are fhiorous- soluble and/or organize at interfaces between a fhiorous phase and a non-fluorous phase. In some embodiments, emulsions or films are provided comprising a polymer. The polymers, emulsions, and films can be used in many applications, including for determining, treating, and/or imaging a condition and/or disease in a subject. The polymer may also be incorporated into various optoelectronic device such as photovoltaic cells, organic light-emitting diodes, organic field effect transistors, or the like. In some embodiments, the polymers comprise pi-conjugated backbones, and in some cases, are highly emissive.