| 1430639-03-4

• 分子结构分类: 有机化合物 - 苯类化合物 - N-苯基羟胺
• CAS: 1430639-03-4
• 化学式: C₇H₈*C₄₆H₆₀CoN₂O₂
• 分子量: 824.128
• InChiKey: FFHLDZOONKAILG-SMLMNLRHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 甲苯 、 cobalt(II) bromide 以 四氢呋喃 为溶剂， 反应 12.0h， 以67%的产率得到
  参考文献：
  名称：

  Molecular structure and spectroscopy of divalent first row transition metals, Mn–Zn, with salicylaldiminate ligands

  摘要：

  The synthesis and spectroscopy of divalent first row transition metals bearing two monoanionic salicylaldiminate ligands is reported. The reaction of MnCl2, FeCl2, CoBr2, 1,2-(Ph2PCH2CH2PPh2)NiCl2, and CuCl2 with 2 equiv. of the alkali metal salt of [(OC6H2Bu2C)-Bu-t(H)=N(C6H3Me2)](1-) produces the corresponding M[(OC6H2Bu2C)-Bu-t(H)=N(C6H3Me2)](2), M = Mn, Fe, Co, Ni, and Cu. Reaction of ZnEt2 with 2 equiv. of the protonated ligand affords Zn[(OC6H2Bu2C)-Bu-t(H)=N(C6H3Me2)](2). The molecular structure of each complex has been analyzed using IR spectroscopy and X-ray crystallography while UV-Vis, CW-EPR, solution magnetic susceptibilities, and OFT calculations were also used to probe their electronic structure. Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2013.02.011