4,8-dibromo-1,5-ditoluene-p-sulfonamidonaphthalene | 102754-01-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,8-dibromo-1,5-ditoluene-p-sulfonamidonaphthalene
• 英文别名: N,N'-(4,8-dibromo-naphthalene-1,5-diyl)-bis-toluene-4-sulfonamide；N,N'-(4,8-Dibrom-naphthalin-1,5-diyl)-bis-toluol-4-sulfonamid；N-[4,8-dibromo-5-[(4-methylphenyl)sulfonylamino]naphthalen-1-yl]-4-methylbenzenesulfonamide
• CAS: 102754-01-8
• 化学式: C₂₄H₂₀Br₂N₂O₄S₂
• 分子量: 624.374
• InChiKey: UUHCZYBQZGSSAK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4,8-dibromo-1,5-ditoluene-p-sulfonamidonaphthalene 在 硫酸 、 溴 、 碘 、 sodium nitrite 作用下， 生成 1,3,5,8-tetrabromonaphthalene
  参考文献：
  名称：

  46.萘二胺的取代反应。第二部分 1：5-和1：8-萘二胺的二甲苯-对磺酰基衍生物的溴化

  摘要：

  DOI：

  10.1039/jr9510000221
• 作为产物：
  描述：

  1,5-bis(p-toluenesulfonamido)naphthalene 在 溴 、 溶剂黄146 作用下， 生成 4,8-dibromo-1,5-ditoluene-p-sulfonamidonaphthalene
  参考文献：
  名称：

  46.萘二胺的取代反应。第二部分 1：5-和1：8-萘二胺的二甲苯-对磺酰基衍生物的溴化

  摘要：

  DOI：

  10.1039/jr9510000221

文献信息

• Substituted naphtho[1,8-de:5,4-d'e']bis[1,3]thiazines, process for their
  申请人：Ciba-Geigy Corporation

  公开号：US05349062A1

  公开（公告）日：1994-09-20

  Compounds of formula I ##STR1## wherein X.sub.1 and X.sub.2 are each independently of the other O, S or Se, and R.sub.1 and R.sub.2 are each independently of the other a monovalent radical of an aliphatic or aromatic hydrocarbon of 1 to 20 carbon atoms which is unsubstituted or substituted by NH.sub.2, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, phenyl or C.sub.3 -C.sub.8 cycloalkyl. The compounds of formula I are able to form electrically conductive charge transfer complexes.

  式I的化合物 ##STR1## 其中X.sub.1和X.sub.2各自独立地为O、S或Se，而R.sub.1和R.sub.2各自独立地为1到20个碳原子的脂肪或芳香族碳氢化合物的一价基团，该基团未被取代或被NH.sub.2、C.sub.1-C.sub.6烷基、C.sub.1-C.sub.6烷氧基、苯基或C.sub.3-C.sub.8环烷基取代。式I的化合物能够形成电导电荷转移复合物。
• Organic electroluminescence element
  申请人：Yamagata Promotional Organization for Industrial Technology

  公开号：EP2075305A2

  公开（公告）日：2009-07-01

  An organic EL element having one or a plurality of organic layers including a light emitting layer between a pair of electrodes is arranged such that at least one layer of the above-mentioned organic layers contains a compound as expressed by the following general formula (1) independently or as a mixture. (where, R1-R4 are selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, and an aryloxy group, and they may be the same groups or the groups different from one another, and A1-A4 are selected from the group consisting of a phenyl group which is either substituted or unsubstituted and a 5 or 6 member heterocyclic ring group which is either substituted or unsubstituted, and they may be the same groups or the groups different from one another.)

  有机电致发光元件具有一个或多个有机层，其中包括位于一对电极之间的发光层，其布置方式为上述有机层中至少有一层单独或作为混合物含有下式（1）表示的化合物。 (其中，R1-R4选自由氢、烷基、环烷基、烷氧基、环烷氧基和芳氧基组成的组，它们可以是相同的基团，也可以是彼此不同的基团；A1-A4选自由取代或未取代的苯基和取代或未取代的5或6个杂环组成的组，它们可以是相同的基团，也可以是彼此不同的基团)。
• Organic thin-film transistor and method for manufacturing same
  申请人：FUJIFILM Corporation

  公开号：US10008671B2

  公开（公告）日：2018-06-26

  Provided are an organic thin-film transistor including: a gate electrode, an organic semiconductor layer, a gate insulating layer, and a source electrode and a drain electrode on a substrate, in which the organic semiconductor layer contains an organic semiconductor and a block copolymer, and the block copolymer is at least one selected from specific block copolymers such as a styrene-(meth)acrylate ester block copolymer and may be phase-separated, and a method for manufacturing an organic thin-film transistor, which includes an organic semiconductor containing a phase-separated block copolymer, including: applying a coating solution which contains an organic semiconductor and a block copolymer for film formation; and heating the obtained film so that the block copolymer is self-assembled.

  提供了一种有机薄膜晶体管，包括：栅极、有机半导体层、栅极绝缘层以及基底上的源电极和漏电极，其中有机半导体层包含有机半导体和嵌段共聚物，嵌段共聚物至少是选自特定嵌段共聚物（如苯乙烯-（甲基）丙烯酸酯嵌段共聚物）中的一种，并且可以是相分离的；以及一种制造有机薄膜晶体管的方法，其中包括含有相分离嵌段共聚物的有机半导体，包括： 1：涂敷含有有机半导体和嵌段共聚物的涂层溶液，以形成薄膜；以及加热获得的薄膜，使嵌段共聚物自组装。
• Zambounis, John S.; Christen, Edgar; Pfeiffer, Jürgen, Journal of the American Chemical Society, 1994, vol. 116, # 3, p. 925 - 931
  作者：Zambounis, John S.、Christen, Edgar、Pfeiffer, Jürgen、Rihs, Grety

  DOI：——

  日期：——
• Notes - Preparation of 1,5-Dibromo-4,8-diiodonaphthalene
  作者：Robert Bayer、Edward O'Reilly, Jr.

  DOI：10.1021/jo01099a603

  日期：1958.5