4-[2-[[4-(dimethylamino)phenyl]methylideneamino]ethyliminomethyl]-N,N-dimethylaniline | 81512-54-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-[2-[[4-(dimethylamino)phenyl]methylideneamino]ethyliminomethyl]-N,N-dimethylaniline
• 英文别名: N,N'-bis-(4-dimethylamino-benzyliden)-ethylenediamine；N,N'-Bis-(4-dimethylamino-benzyliden)-aethylendiamin
• CAS: 81512-54-1
• 化学式: C₂₀H₂₆N₄
• 分子量: 322.453
• InChiKey: AOXCQFSEIDWMSU-YHARCJFQSA-N

物化性质

• 熔点：
  179-180 °C
• 沸点：
  481.7±40.0 °C(Predicted)
• 密度：
  0.99±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.36
• 重原子数：
  24.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  31.2
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  巯基乙酸 、 4-[2-[[4-(dimethylamino)phenyl]methylideneamino]ethyliminomethyl]-N,N-dimethylaniline 以 苯 为溶剂， 反应 4.0h， 生成 2-[4-(dimethylamino)phenyl]-3-[2-[2-[4-(dimethylamino)phenyl]-4-oxo-1,3-thiazolidin-3-yl]ethyl]-1,3-thiazolidin-4-one
  参考文献：
  名称：

  Praharaj; Dash; Mohapatra, Journal of the Indian Chemical Society, 1981, vol. 58, # 12, p. 1184 - 1186

  摘要：

  DOI：
• 作为产物：
  描述：

  乙二胺 、 对二甲氨基苯甲醛 以 苯 为溶剂， 生成 4-[2-[[4-(dimethylamino)phenyl]methylideneamino]ethyliminomethyl]-N,N-dimethylaniline
  参考文献：
  名称：

  Praharaj; Dash; Mohapatra, Journal of the Indian Chemical Society, 1981, vol. 58, # 12, p. 1184 - 1186

  摘要：

  DOI：

文献信息

• Method of forming a carbon-carbon or carbon-heteroatom linkage
  申请人：Taillefer Marc

  公开号：US20050234239A1

  公开（公告）日：2005-10-20

  The invention relates to a method of creating a carbon-carbon or carbon-heteroatom linkage by reacting an unsaturated compound bearing a leaving group and a nucleophilic compound. More specifically, the invention relates to the creation of a carbon-nitrogen linkage involving the arylation of nitrogenous organic derivatives. The inventive method consists in creating a carbon-carbon or carbon-heteroatom linkage by reacting an unsaturated compound bearing a leaving group and a nucleophilic compound providing a carbon atom or a heteroatom (HE) capable of being substituted for the leaving group, thereby creating a C—C or C-HE linkage. The invention is characterised in that the reaction is carried out in the presence of an effective quantity of a catalyst based on copper and at least one ligand comprising at least one imine function and at least one additional nitrogen atom as chelating atoms

  该发明涉及一种通过使带有离去基团和亲核化合物的不饱和化合物发生反应来创建碳-碳或碳-杂原子键的方法。更具体地，该发明涉及涉及通过芳基化氮有机衍生物来创建碳-氮键。该创新方法包括通过使带有离去基团和提供能够替代离去基团的碳原子或杂原子（HE）的亲核化合物发生反应来创建碳-碳或碳-杂原子键。该发明的特点在于，在铜基催化剂和至少包含至少一个亚胺功能和至少一个额外氮原子作为螯合原子的配体的有效量存在下进行反应。
• Eckstein; Lukasiewicz, Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, 1959, vol. 7, p. 789,790,795
  作者：Eckstein、Lukasiewicz

  DOI：——

  日期：——
• DASH, B.;PRAHARAJ, S.;MOHAPATRA, P. K., J. INDIAN CHEM. SOC., 1981, 58, N 12, 1184-1186
  作者：DASH, B.、PRAHARAJ, S.、MOHAPATRA, P. K.

  DOI：——

  日期：——
• FUNCTIONALIZED POLYMER AND METHOD FOR MAKING
  申请人：Yan Yuan-Yong

  公开号：US20080154020A1

  公开（公告）日：2008-06-26

  A functionalized polymer includes a directly bonded moiety, which can be located at a terminus of the polymer, defined by the formula —CR 1 R 2 NH-Q-M where M is (N═CR 1 R 2 ) or N-(QN═CR 1 R 2 ) 2 each Q independently is a substituted or unsubstituted, cyclic or acyclic C 1 -C 40 alkyl, aryl, or alkaryl radical, and each R 1 and R 2 independently is a hydrogen atom or a substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, allyl, aralkyl, alkaryl, or alkynyl group. The polymer can be provided by introducing a polyimine compound into a system that includes carbanionic (living) polymer. Such polymers can be used in the production of compositions that include particulate fillers.
• US8853352B2
  申请人：——

  公开号：US8853352B2

  公开（公告）日：2014-10-07