η6-(ethylphenylacetate)-η5-cyclopentadienyliron hexafluorophosphate | 107407-25-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: η6-(ethylphenylacetate)-η5-cyclopentadienyliron hexafluorophosphate
• 英文别名: (η5-cyclopentadienyl)iron(ethyl-2-phenylacetate) hexafluorophosphate；cyclopenta-1,3-diene;ethyl 2-phenylacetate;iron(2+);hexafluorophosphate
• CAS: 107407-25-0
• 化学式: C₁₅H₁₇FeO₂*F₆P
• 分子量: 430.11
• InChiKey: VSGWFWFVDMEWHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  η6-(ethylphenylacetate)-η5-cyclopentadienyliron hexafluorophosphate 、 碘甲烷 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以32%的产率得到(η5-cyclopentadienyl)iron(ethyl-2,2-dimethyl-2-phenylacetate) hexafluorophosphate
  参考文献：
  名称：

  Al2O3-mediated deacetylation of CpFe(ethyl-2-phenylacetoacetate) hexafluorophosphate

  摘要：

  Passage of the title compound through a short column of Al2O3 induces deacetylation to form CpFe(ethyl-2-phenylacetate) hexafluorophosphate. This compound is shown to react with base to generate the stabilized enolate, which is dideuteriated or dimethylated upon quenching with excess D2O or CH3I. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00523-4
• 作为产物：
  描述：

  (η5-cyclopentadienyl)iron(ethyl-2-phenylacetoacetate)hexafluorophosphate 在 aluminum oxide 作用下， 以 二氯甲烷 为溶剂， 生成 η6-(ethylphenylacetate)-η5-cyclopentadienyliron hexafluorophosphate
  参考文献：
  名称：

  Al2O3-mediated deacetylation of CpFe(ethyl-2-phenylacetoacetate) hexafluorophosphate

  摘要：

  Passage of the title compound through a short column of Al2O3 induces deacetylation to form CpFe(ethyl-2-phenylacetate) hexafluorophosphate. This compound is shown to react with base to generate the stabilized enolate, which is dideuteriated or dimethylated upon quenching with excess D2O or CH3I. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00523-4

文献信息

• Gill, U. S.; Moriarty, R. M., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1986, vol. 16, p. 485 - 490
  作者：Gill, U. S.、Moriarty, R. M.

  DOI：——

  日期：——