2-(hydroxy(phenyl)(pyridin-2-yl)methyl)methoxybenzene | 1318655-68-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(hydroxy(phenyl)(pyridin-2-yl)methyl)methoxybenzene
• 英文别名: (2-Methoxyphenyl)-phenyl-pyridin-2-ylmethanol；(2-methoxyphenyl)-phenyl-pyridin-2-ylmethanol
• CAS: 1318655-68-3
• 化学式: C₁₉H₁₇NO₂
• 分子量: 291.349
• InChiKey: CCAUHCPAMCFMKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  42.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(hydroxy(phenyl)(pyridin-2-yl)methyl)methoxybenzene 、 copper dichloride 以 甲醇 、 丙酮 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Highly flexible O,O′,N ligands and their Fe, Ni, Cu and Zn complexes

  摘要：

  Three new chiral ligands bearing an O,O',N donor set (OmethoxyOhydroxyNpyridine) were synthesised and coordinated to Fe-III, Fe-II, Ni-II, Cu-II and Zn-II to yield complexes with the general formula [M(OON)Cl-x](y). While the pyridine N and the hydroxy O atoms coordinate strongly to all applied metal ions, the methoxy donor seems not to be involved in coordination, although some evidence for a weak interaction between O-Me and the Zn-II were found in NMR spectra. In the bidentate O', N coordination mode the new ligands exhibit several coordination geometries as analysed in the solid compounds by XRD, EXAFS and EPR and in solution by UV-Vis absorption, cyclic voltammetry, EXAFS, EPR or NMR spectroscopy. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.072
• 作为产物：
  描述：

  2-苯甲酰吡啶 、 2-碘苯甲醚 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 以72%的产率得到2-(hydroxy(phenyl)(pyridin-2-yl)methyl)methoxybenzene
  参考文献：
  名称：

  Highly flexible O,O′,N ligands and their Fe, Ni, Cu and Zn complexes

  摘要：

  Three new chiral ligands bearing an O,O',N donor set (OmethoxyOhydroxyNpyridine) were synthesised and coordinated to Fe-III, Fe-II, Ni-II, Cu-II and Zn-II to yield complexes with the general formula [M(OON)Cl-x](y). While the pyridine N and the hydroxy O atoms coordinate strongly to all applied metal ions, the methoxy donor seems not to be involved in coordination, although some evidence for a weak interaction between O-Me and the Zn-II were found in NMR spectra. In the bidentate O', N coordination mode the new ligands exhibit several coordination geometries as analysed in the solid compounds by XRD, EXAFS and EPR and in solution by UV-Vis absorption, cyclic voltammetry, EXAFS, EPR or NMR spectroscopy. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.072

文献信息

• Highly flexible O,O′,N ligands and their Fe, Ni, Cu and Zn complexes
  作者：Katharina Butsch、Axel Klein、Matthias Bauer

  DOI：10.1016/j.ica.2011.02.072

  日期：2011.8

  Three new chiral ligands bearing an O,O',N donor set (OmethoxyOhydroxyNpyridine) were synthesised and coordinated to Fe-III, Fe-II, Ni-II, Cu-II and Zn-II to yield complexes with the general formula [M(OON)Cl-x](y). While the pyridine N and the hydroxy O atoms coordinate strongly to all applied metal ions, the methoxy donor seems not to be involved in coordination, although some evidence for a weak interaction between O-Me and the Zn-II were found in NMR spectra. In the bidentate O', N coordination mode the new ligands exhibit several coordination geometries as analysed in the solid compounds by XRD, EXAFS and EPR and in solution by UV-Vis absorption, cyclic voltammetry, EXAFS, EPR or NMR spectroscopy. (C) 2011 Elsevier B.V. All rights reserved.