K[PtPh2(3,5-bis(4-methoxyphenyliminoacetyl)-4-methylpyrazolato)] | 1065476-57-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: K[PtPh2(3,5-bis(4-methoxyphenyliminoacetyl)-4-methylpyrazolato)]
• CAS: 1065476-57-4
• 化学式: C₃₄H₃₃KN₄O₂Pt
• 分子量: 763.84
• InChiKey: MFTMFLZWGTVQOS-LBDSJRNRSA-N

反应信息

• 作为反应物：
  描述：

  copper(l) chloride 、 K[PtPh2(3,5-bis(4-methoxyphenyliminoacetyl)-4-methylpyrazolato)] 以 乙腈 为溶剂， 以88%的产率得到Cu2[PtPh2(3,5-bis(4-methoxyphenyliminoacetyl)-4-methylpyrazolato)]
  参考文献：
  名称：

  Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands

  摘要：

  The reaction of symmetrical dinucleating ligands 3,5-bis(4-methoxyphenyliminoacetyl)-4-methylpyrazole (bmimpH, 1a) and 3,5-bis(2,6-dimethylphenyliminoacetyl)-4-methylpyrazole (bdmimpH, 1b) with [(mu-Me2S)PtMe2](2) or (Me2S)(2)PtPh2 affords selectively mononuclear complexes LPtMe(SMe2) or LPtPh(SMe2) (L = bmimp, bdmimp). Reaction of these complexes with CuCl gives access to ionic compounds {[LPtMe(SMe2)](2)Cu+CuCl2- and [LPtPh(SMe2)](Cu+CuCl2-)-Cu-2, which exhibit dynamic behavior in solution for L = bdmimp. Ligand deprotonation followed by reaction with (Me2S)(2)PtPh2 affords mononuclear anionic complexes K+[LPtPh2](-). These react with CuCl to give dimeric structures of formula {[LPtPh2](2)Cu-2}, which exhibit Pt -> Cu dative bonds and a Cu-Cu contact, and dynamic behavior in solution.

  DOI：

  10.1021/om800403y
• 作为产物：
  描述：

  苯基锂 以 乙醚 、 二氯甲烷 、 二丁醚 为溶剂， 生成 K[PtPh2(3,5-bis(4-methoxyphenyliminoacetyl)-4-methylpyrazolato)]
  参考文献：
  名称：

  Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands

  摘要：

  The reaction of symmetrical dinucleating ligands 3,5-bis(4-methoxyphenyliminoacetyl)-4-methylpyrazole (bmimpH, 1a) and 3,5-bis(2,6-dimethylphenyliminoacetyl)-4-methylpyrazole (bdmimpH, 1b) with [(mu-Me2S)PtMe2](2) or (Me2S)(2)PtPh2 affords selectively mononuclear complexes LPtMe(SMe2) or LPtPh(SMe2) (L = bmimp, bdmimp). Reaction of these complexes with CuCl gives access to ionic compounds {[LPtMe(SMe2)](2)Cu+CuCl2- and [LPtPh(SMe2)](Cu+CuCl2-)-Cu-2, which exhibit dynamic behavior in solution for L = bdmimp. Ligand deprotonation followed by reaction with (Me2S)(2)PtPh2 affords mononuclear anionic complexes K+[LPtPh2](-). These react with CuCl to give dimeric structures of formula {[LPtPh2](2)Cu-2}, which exhibit Pt -> Cu dative bonds and a Cu-Cu contact, and dynamic behavior in solution.

  DOI：

  10.1021/om800403y