2,6-(MeOCH2)2C6H3SbCl2 | 910230-46-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-(MeOCH2)2C6H3SbCl2
• 英文别名: [2,6-Bis(methoxymethyl)phenyl]-dichlorostibane
• CAS: 910230-46-5
• 化学式: C₁₀H₁₃Cl₂O₂Sb
• 分子量: 357.868
• InChiKey: OFFYYIJCOOTVBY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.15
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,6-(MeOCH2)2C6H3SbCl2 、 silver(I) acetate 以 二氯甲烷 为溶剂， 以69%的产率得到2,6-(MeOCH2)2C6H3Sb(acetate)2
  参考文献：
  名称：

  Intramolecularly coordinated organoantimony(III) carboxylates

  摘要：

  The reactions of organoantimony chlorides (LSbCl2)-Sb-1,2 1 and 2 ([2,6-(ROCH2)(2)C6H3](-), R = Me; L-1 and R = t-Bu; L-2) with silver salts of selected carboxylic acids resulted to corresponding organoantimony carboxylates L-1,L-2 Sb(OOCR')(2), 1a-c (for L-1) and 2a-c (for L-2), where R'= CH3 for la, 2a; R' = CH=CH2 for 1b, 2b and R'= CF3 for 1c, 2c. All compounds were characterized by the help of elemental analysis, ESI-MS, H-1 and C-13 NMR spectroscopy. The solid state structure investigation using single crystal X-ray diffraction techniques (2a, c) and IR spectroscopy revealed significant differences in coordination mode of both O,C,O chelating ligand and carboxylic groups in this set of compounds. The structure of all compounds in solution of non-coordinating solvent (CDCl3) was determined by means of variable temperature H-1, C-13, F-19 NMR spectroscopy and IR spectroscopy. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.005

文献信息

• Intramolecularly coordinated organoantimony(III) carboxylates
  作者：Lubomír Machuča、Libor Dostál、Roman Jambor、Karel Handlíř、Robert Jirásko、Aleš Růžička、Ivana Císařová、Jaroslav Holeček

  DOI：10.1016/j.jorganchem.2007.06.005

  日期：2007.8

  The reactions of organoantimony chlorides (LSbCl2)-Sb-1,2 1 and 2 ([2,6-(ROCH2)(2)C6H3](-), R = Me; L-1 and R = t-Bu; L-2) with silver salts of selected carboxylic acids resulted to corresponding organoantimony carboxylates L-1,L-2 Sb(OOCR')(2), 1a-c (for L-1) and 2a-c (for L-2), where R'= CH3 for la, 2a; R' = CH=CH2 for 1b, 2b and R'= CF3 for 1c, 2c. All compounds were characterized by the help of elemental analysis, ESI-MS, H-1 and C-13 NMR spectroscopy. The solid state structure investigation using single crystal X-ray diffraction techniques (2a, c) and IR spectroscopy revealed significant differences in coordination mode of both O,C,O chelating ligand and carboxylic groups in this set of compounds. The structure of all compounds in solution of non-coordinating solvent (CDCl3) was determined by means of variable temperature H-1, C-13, F-19 NMR spectroscopy and IR spectroscopy. (c) 2007 Elsevier B.V. All rights reserved.