11'-Phenylspiro[fluorene-9,14'-pentacyclo[11.7.0.02,10.03,8.015,20]icosa-1(13),2(10),3,5,7,11,15,17,19-nonaene]-9'-one | 1265227-99-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 11'-Phenylspiro[fluorene-9,14'-pentacyclo[11.7.0.02,10.03,8.015,20]icosa-1(13),2(10),3,5,7,11,15,17,19-nonaene]-9'-one
• 英文别名: 11'-phenylspiro[fluorene-9,14'-pentacyclo[11.7.0.02,10.03,8.015,20]icosa-1(13),2(10),3,5,7,11,15,17,19-nonaene]-9'-one
• CAS: 1265227-99-3
• 化学式: C₃₈H₂₂O
• 分子量: 494.592
• InChiKey: SWCLOEHNJVPYPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  39
• 可旋转键数：
  1
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  11'-Phenylspiro[fluorene-9,14'-pentacyclo[11.7.0.02,10.03,8.015,20]icosa-1(13),2(10),3,5,7,11,15,17,19-nonaene]-9'-one 在 正丁基锂 、 potassium hydroxide 、 肼 作用下， 以 四氢呋喃 、 二乙二醇 为溶剂， 反应 4.5h， 生成 9',9'-Diethyl-11'-phenylspiro[fluorene-9,14'-pentacyclo[11.7.0.02,10.03,8.015,20]icosa-1(13),2(10),3,5,7,11,15,17,19-nonaene]
  参考文献：
  名称：

  Novel dispirobifluorenes and indeno-spirobifluorenes: syntheses and properties

  摘要：

  Novel indeno-spirobifluorene and dispirobifluorene derivatives were synthesized and characterized. Their two positional isomers were unambiguously determined by X-ray crystallography. Preliminary investigations indicated that these indeno-spirobifluorene and dispirobifluorenes showed blue fluorescence with good quantum yields (Phi>60%) and excellent thermal stabilities. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.11.092
• 作为产物：
  描述：

  9-乙炔-9-芴醇 在 溶剂黄146 作用下， 反应 2.17h， 生成 11'-Phenylspiro[fluorene-9,14'-pentacyclo[11.7.0.02,10.03,8.015,20]icosa-1(13),2(10),3,5,7,11,15,17,19-nonaene]-9'-one
  参考文献：
  名称：

  Novel dispirobifluorenes and indeno-spirobifluorenes: syntheses and properties

  摘要：

  Novel indeno-spirobifluorene and dispirobifluorene derivatives were synthesized and characterized. Their two positional isomers were unambiguously determined by X-ray crystallography. Preliminary investigations indicated that these indeno-spirobifluorene and dispirobifluorenes showed blue fluorescence with good quantum yields (Phi>60%) and excellent thermal stabilities. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.11.092

文献信息

• Novel dispirobifluorenes and indeno-spirobifluorenes: syntheses and properties
  作者：Yingbo Shi、Qiancai Liu、Guohong Wu、Lingling Rong、Jie Tang

  DOI：10.1016/j.tet.2010.11.092

  日期：2011.2

  Novel indeno-spirobifluorene and dispirobifluorene derivatives were synthesized and characterized. Their two positional isomers were unambiguously determined by X-ray crystallography. Preliminary investigations indicated that these indeno-spirobifluorene and dispirobifluorenes showed blue fluorescence with good quantum yields (Phi>60%) and excellent thermal stabilities. (C) 2010 Elsevier Ltd. All rights reserved.