[Cu(4,6,6-trimethyl-1,9-diamino-3,7-diaza-nona-3-ene)][ZnCl4] | 51455-96-0

• 英文名称: [Cu(4,6,6-trimethyl-1,9-diamino-3,7-diaza-nona-3-ene)][ZnCl4]
• 英文别名: [(4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-ene)tetrachlorozinc(II)copper(II)]
• CAS: 51455-96-0；867347-34-0
• 化学式: C₁₀H₂₄CuN₄*Cl₄Zn
• 分子量: 471.075
• InChiKey: WEDJMTRSEWJSQK-HDIYTVQXSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(4,6,6-trimethyl-1,9-diamino-3,7-diaza-nona-3-ene)][ZnCl4] 以 neat (no solvent) 为溶剂， 生成 zinc(II) chloride
  参考文献：
  名称：

  Catalytic electroreduction of oxygen on products of pyrolysis of heterobimetallic complexes of zinc

  摘要：

  Electrocatalysts for reduction of oxygen were synthesized from AG-3 activated carbon promoted with pyrolized heterobimetallic complexes. [CoLCl2] [ZnDMFACl(3)] and [ML][ZnCl4] (M = CU Ni2+; L = 4,6,6-trimethyl-1,9-dimino-3,7-diaza-nona-3-ene). The optimal conditions of synthesis of the catalysts, which affect the efficiency of oxygen electroreduction, were found and the activity series of the catalyst in relation to the nature of the second metal was determined.

  DOI：

  10.1134/s1070427206120111
• 作为产物：
  描述：

  1,2-diaminoethane dihydrochloride 、 铜 、 丙酮 、 zinc(II) oxide 以 丙酮 、 乙腈 为溶剂， 以82%的产率得到[Cu(4,6,6-trimethyl-1,9-diamino-3,7-diaza-nona-3-ene)][ZnCl4]
  参考文献：
  名称：

  Heterobimetallic M/Zn (M=Cu, Ni) complexes with open-chain N- and N,O-ligands: Template synthesis from metal powders and supramolecular crystal structures

  摘要：

  A series of new heterometallic (CuZnII)-Zn-II and (NiZnII)-Zn-II complexes with N- and N,O open-chain multidentate ligands (L-1 = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-ene; L-2 = 3,7-bis(2-aminoethyl)-1,3,5,7-tetraazabicyclo[3.3.1]nonane; L-3 = 1, 15-dihydroxy-7,9,9-trimethyl-3,6,10,13-tetraazapentadec-6-ene and L-4 = 1-hydroxy-9-oxy-4,6,6-trimethyl-3,7-diazanon-3-ene) have been prepared through the "direct template synthesis" approach, which is a combination of classical template reactions of amines with acetone/formaldehyde and the "direct synthesis" method based on using elemental metals as starting materials. There is a significant decrease in the reaction time when the "direct synthesis" method is used compared to the conventional template condensation methods. X-ray crystallographic analyses of the complexes with the general formula M(L)ZnX4 and [(CuLZnCl3)-Zn-4](2) (M = Cu2+, Ni2+; L = L-1-L-3; X = Cl-, NCS-) reveal the presence of long intermolecular distance interactions, such as semi-coordination, S center dot center dot center dot S and H-bonding, in their crystal organization. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.031