di(pyridine)silver(I) dinitramidate | 160150-98-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: di(pyridine)silver(I) dinitramidate
• 英文别名: silver bis(pyridine) dinitramide；[Ag(py)2](N3O4)
• CAS: 160150-98-1
• 化学式: C₁₀H₁₀AgN₂*N₃O₄
• 分子量: 372.089
• InChiKey: FIAUJXFJLFFBCE-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  甲基锂 、 di(pyridine)silver(I) dinitramidate 在 TeCl₄ 作用下， 以 水 为溶剂， 生成 lithium dinitramidate monohydrate
  参考文献：
  名称：

  Oxygenversusnitrogen interactions in lithium dinitramidate dihydrate and pyridinium dinitramidate

  摘要：

  The title compounds, diaquadinitramidatolithium(I), [Li( N3O4)(H2O)(2)], (I), and pyridinium dinitramidate, C5H6N+ center dot N3O4-, (II), differ significantly in their cation-anion contacts. The Li+ atom of (I) is coordinated by two O atoms of the dinitramide anion in a chelate and by four additional water molecules, with the Li and central N atom of the anion on a twofold rotation axis. The pyridinium cation of (II) exhibits a contact with the dinitramide anion via an intermolecular N-H center dot center dot center dot N hydrogen bridge. These interactions are compared with those found in reported anhydrous lithium dinitramide and ammonium dinitramide salts.

  DOI：

  10.1107/s0108270107054212
• 作为产物：
  描述：

  silver dinitramide 在 pyridine 作用下， 以 乙醇 为溶剂， 以75%的产率得到di(pyridine)silver(I) dinitramidate
  参考文献：
  名称：

  Dinitramide and its salts

  摘要：

  The preparation and physicochemical properties of salts of dinitramide HN(NO2)(2) with uni- and bivalent metals of groups I, II, VII, and VIII of the Periodic Table are considered.

  DOI：

  10.1007/bf00697125
• 作为试剂：
  描述：

  1-甲基-5-氨基四氮唑 、 碘甲烷 在 di(pyridine)silver(I) dinitramidate 作用下， 以 乙腈 、 甲醇 为溶剂， 生成 5-amino-1,4-dimethyltetrazolium dinitramide
  参考文献：
  名称：

  Energetic Salts of Low‐Symmetry Methylated 5‐Aminotetrazoles

  摘要：

  AbstractIonic salts containing the novel 5‐amino‐2‐methyl‐ and 5‐amino‐1,3‐dimethyltetrazolium cations with energetic anions (perchlorate, nitrate, azide and dinitramide) have been synthesized in high yields and purities and fully characterized. A full structural description by spectroscopic methods (vibrational and 15N NMR spectroscopy) and X‐ray analysis is given. Unexpectedly, salts based on the asymmetric 5‐amino‐1,3‐dimethyltetrazolium cation have higher densities than analogue compounds containing the isomeric 5‐amino‐1,4‐dimethyltetrazolium cation, regardless of the lower symmetry of the former. This can be attributed to secondary interactions between the cation and anion and is reflected in the higher detonation parameters of the new compounds, which represent a new class of nitrogen‐rich, high‐performing materials with low sensitivity and good potential for energetic applications. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200800995

文献信息

• ——
  作者：How-Ghee Ang、Wolfgang Fraenk、Konstantin Karaghiosoff、Thomas M. Klapötke、Peter Mayer、Heinrich Nöth、Joanna Sprott、Marcus Warchhold

  DOI：10.1002/1521-3749(200213)628:13<2894::aid-zaac2894>3.0.co;2-r

  日期：——

  The literature known, but not fully characterized, silver dinitramide transfer reagents AgN(NO2)(2) (1), [Ag(NCCH3)]-[N(NO2)(2)] (2), and [Ag(py)(2)][N(NO2)(2)] (3) have been investigated by Ag-109, N-14 NMR and vibrational spectroscopy (IR, Raman). In addition, the poorly understood [Cu(NH3)(4)][N(NO2)(2))](2) (4) and [Pd(NH3)(4)][N(NO2)(2)](2), (5) have also been prepared and characterized by N-14 NMR and vibrational spectroscopy (IR, Raman). The structures of 2-5 have also been determined by X-ray diffraction.