hexakis{9;10,16;17,23;24-(1,2-bis-(diethylaminoethylthiol))-2-(4-phenoxycarboxy)phthalocyanine} Zn | 475096-26-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: hexakis{9;10,16;17,23;24-(1,2-bis-(diethylaminoethylthiol))-2-(4-phenoxycarboxy)phthalocyanine} Zn
• CAS: 475096-26-5
• 化学式: C₇₅H₉₈N₁₄O₃S₆Zn
• 分子量: 1501.48
• InChiKey: XXXPYZHEIZYRMG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2-bis(2-(diethylamino)ethylsulfanyl)-4,5-dicyanobenzene 、 4-(3,4-dicyanophenoxy)benzoic acid 、 zinc(II) chloride 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 7.0h， 以15.1%的产率得到hexakis{9;10,16;17,23;24-(1,2-bis-(diethylaminoethylthiol))-2-(4-phenoxycarboxy)phthalocyanine} Zn
  参考文献：
  名称：

  Photodynamic inactivation of Staphylococcus aureus using low symmetrically substituted phthalocyanines supported on a polystyrene polymer fiber

  摘要：

  This work reports on the antimicrobial photo-activities of a series of low symmetrically substituted phthalocyanine complexes in solution and in a fiber matrix. Phthalocyanine complexes were successfully electrospun into a polystyrene polymer. The fiber diameter ranged from 240 nm to 390 nm in average. The modified polymer fiber showed successful singlet oxygen production with the Ge monocarboxy phthalocyanine modified fiber giving the highest singlet oxygen quantum yield value of 0.46 due to lack of aggregation when in the polymer. All the unsymmetrically substituted complexes showed antimicrobial activity towards S. Aureus under illumination with visible light. The symmetrical ZnPc and ZnTPCPc showed no activity under illumination with light in the fiber matrix due to low singlet oxygen production. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.10.001