缩水甘油基辛酸酯 | 24412-91-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 缩水甘油基辛酸酯
• 中文别名: 辛酸缩水甘油酯
• 英文名称: glycidyl octanoate
• 英文别名: octanoyloxymethyl-oxirane；Oxiran-2-ylmethyl octanoate
• CAS: 24412-91-7
• 化学式: C₁₁H₂₀O₃
• 分子量: 200.278
• InChiKey: CCNCFYINOYWDOK-UHFFFAOYSA-N

物化性质

• 沸点：
  267.4±13.0 °C(Predicted)
• 密度：
  0.996±0.06 g/cm3(Predicted)
• 溶解度：
  氯仿（微溶）、乙酸乙酯（微溶）

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  缩水甘油基辛酸酯 在 硫脲 作用下， 以55%的产率得到Octanoic acid thiiranylmethyl ester
  参考文献：
  名称：

  某些一元羧酸硫缩水甘油酯的合成

  摘要：

  DOI：

  10.1007/bf00482488
• 作为产物：
  描述：

  缩水甘油 、 辛酰氯 在 4-二甲氨基吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以91%的产率得到缩水甘油基辛酸酯
  参考文献：
  名称：

  Library of 1,4-Disubstituted 1,2,3-Triazole Analogs of Oxazolidinone RNA-Binding Agents

  摘要：

  The design and synthesis of small molecules that target RNA is immensely important in antibacterial therapy. We had previously reported on the RNA binding of a series of 4,5-disubstituted 2-oxazolidinones that bind to a highly conserved bulge region of bacterial RNA. This biological target T box antitermination system, which is found mainly in Gram-positive bacteria, regulates the expression of several amino acid related genes. In an effort to amplify our library, we have prepared a library of I,4-disubstituted 1,2,3-triazole analogs that entails an isosteric replacement of the oxazolidinone nucleus. The synthesis of the new analogs was enhanced via copper(I) catalysis of an azide and alkyne cycloaddition reaction. A total of 108 1,4-disubstituted 1,2,3-triazole compounds have been prepared. All compounds were evaluated as RNA binding agents.

  DOI：

  10.1021/cc100029y

文献信息

• Radical chlorinations of triglycerides
  作者：Philip E. Sonnet、Stanley Osman

  DOI：10.1007/bf02541098

  日期：1995.3

  Several triglycerides were synthesized with an iodoaroyl group. Intramolecular radical chain transfer chlorinations were conducted that resulted in the associated pair of fatty acids of the triglyceride becoming chlorinated. The distribution of monochlorinated species was similar to that obtained by direct radical chlorination of the relevant fatty acid methyl esters. Functionalization was, as expected, away from the carboxylate group but gave no indication that either alignment of chains or the constraints of an intramolecular process could limit the manifold of products of the reaction. To gauge the effect on halogenation of a structure, bearing more than one electron‐withdrawing group, methyl oleate was converted to thebis trifluoroacetate of methyl 9,10‐dihydroxystearate. No products of chlorination on carbons 2–8 were observed.

  摘要 合成了几种带有碘代芳酰基的甘油三酯。通过分子内自由基链转移氯化反应，使甘油三酯中相关的一对脂肪酸发生氯化。单氯化物种的分布与相关脂肪酸甲酯直接自由基氯化的结果相似。正如预期的那样，官能化远离羧酸基，但没有迹象表明链的排列或分子内过程的限制会限制反应产物的多样性。为了衡量含有一个以上电子抽取基团的结构对卤化的影响，将油酸甲酯转化为 9,10-二羟基硬脂酸甲酯的双三氟乙酸盐。在碳 2 至 8 上没有观察到氯化产物。
• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Organic Electronic Material, Ink Composition Containing Same, and Organic Thin Film, Organic Electronic Element, Organic Electroluminescent Element, Lighting Device, and Display Device Formed Therewith
  申请人：Funyuu Shigeaki

  公开号：US20120074360A1

  公开（公告）日：2012-03-29

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  提供了以下内容：一种有机电子材料，可以轻松地多层堆叠，并可用于无法在高温下加工的基板，例如树脂；包含相同材料的墨水组合物；使用该有机电子材料或该墨水组合物形成的有机薄膜；以及使用该有机薄膜形成的有机电子元件和有机EL元件，其具有比传统元件更优异的发光效率和发射寿命。具体而言，提供了一种有机电子材料，其特征在于包含具有分支结构且向三个或更多方向分支的寡聚物或聚合物，并具有至少一个可聚合取代基；包含该有机电子材料的墨水组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了包含该有机薄膜的有机电子元件和有机电致发光元件。
• Polymerizable molding liquid resins, compositions containing the same and in-mold cured products therefrom
  申请人：Takemoto Yushi Kabushiki Kaisha

  公开号：EP0507597A1

  公开（公告）日：1992-10-07

  Radical polymerizable liquid resins contain unsaturated urethane of a specified structure and vinyl monomers at weight ratio of (unsaturated urethane)/(vinyl monomers)of from 10/90 to 90/10. The unsaturated urethane has (meth)acryloyl and higher aliphatic hydrocarbon groups in its molecule, and the vinyl monomers are copolymerizable with this unsaturated urethane. Radical polymerizable liquid resin compositions are obtained by adding inorganic powder filler to such radical polymerizable liquid resins. In-mold cured products obtained from such radical polymerizable resins or radical polymerizable resin compositions have improved water resistance and other favorable properties.

  可自由基聚合的液体树脂含有特定结构的不饱和聚氨酯和乙烯基单体，其重量比（不饱和聚氨酯）/（乙烯基单体）为 10/90 至 90/10。不饱和聚氨酯分子中含有（甲基）丙烯酰基和较高的脂肪烃基团，乙烯基单体可与不饱和聚氨酯共聚。在这种可自由基聚合的液体树脂中加入无机粉末填料，可得到可自由基聚合的液体树脂组合物。由此类可自由基聚合的树脂或可自由基聚合的树脂组合物制成的模内固化产品具有更好的耐水性和其他有利特性。
• Filler surface modifier
  申请人：Ajinomoto Co., Inc.

  公开号：EP0651032A1

  公开（公告）日：1995-05-03

  Herein disclosed are a filler surface modifier which comprises a phosphoric ester and/or pyrophosphoric ester having a substituent group with a terminal double bond, a filler treated with such a surface modifier, and an unsaturated polyester resin composition and an acrylic resin composition blended with such a surface-treated filler. Such a filler surface modifier eventually not only can increase strength of, namely, provide rigidity for, unsaturated polyester resins filled with CaCO₃ and the like fillers and acrylic resins filled with Al(OH)₃ and the like fillers, but also can reduce viscosity of such resins before curing, thus resulting in improved processability and high filling capacity.

  本文公开了一种由磷酸酯和/或焦磷酸酯组成的填料表面改性剂，该磷酸酯和/或焦磷酸酯具有带有末端双键的取代基团；一种用这种表面改性剂处理过的填料；以及一种不饱和聚酯树脂组合物和一种与这种表面处理过的填料混合的丙烯酸树脂组合物。这种填料表面改性剂最终不仅能提高填充有 CaCO₃等类似填料的不饱和聚酯树脂和填充有 Al（OH）₃等类似填料的丙烯酸树脂的强度，即提供刚度，还能在固化前降低此类树脂的粘度，从而改善加工性能和提高填充能力。