[ReO(OCH3)(oxalato)(1,2-bis(diphenylphosphino)ethylene)] | 400736-38-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [ReO(OCH3)(oxalato)(1,2-bis(diphenylphosphino)ethylene)]
• CAS: 400736-38-1
• 化学式: C₂₉H₂₅O₆P₂Re
• 分子量: 717.668
• InChiKey: FJHODQYYYMIZFQ-BMKZIQKJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 potassium hexabromorhenate (IV) 、 oxalic acid dihydrate 、 顺-1,2-双(二苯基膦)乙烯 在 tris(hydroxylmethyl)aminomethane 作用下， 以 甲醇 为溶剂， 以30%的产率得到[ReO(OCH3)(oxalato)(1,2-bis(diphenylphosphino)ethylene)]
  参考文献：
  名称：

  Oxalato complexes of Re(V). Synthesis and structural characterization of [ReO(OCH3)(ox)(L)] (L=bipy, dppe and dppee)

  摘要：

  Three novel neutral complexes containing the [ReO](3+) core have been prepared starting from K2ReBr6. Complexes with general formula [ReO(OCH3)(ox)(L)] ox=oxalate; L=2,2'-bipyridine (bipy), 1,2-bis(diphenylphosphino)ethane (dppe) or cis-1,2-bis-(diphenylphosphino)ethylene (dppee)) have been obtained and characterized. The molecular structures of [ReO(OCH3)(ox)(bipy)] and [ReO(OCH3)(ox)(dppe)] have been determined of single-crystal X-ray analysis. The structure of the complexes consists of a six-coordinated rhenium atom bonded to two trans-oxygen atoms, one of the [ReO](3+) core and one from a methoxy group. One oxalate ligand and a neutral diamine or diphosphine make the equatorial plane. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00651-x