di([1-(furan-2-yl)ethylidene]-hydrazido)nickel(II) | 758685-26-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: di([1-(furan-2-yl)ethylidene]-hydrazido)nickel(II)
• CAS: 758685-26-6
• 化学式: C₂₄H₂₀N₆NiO₄
• 分子量: 515.151
• InChiKey: SZWDFSWCMJFIPJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [1-(furan-2-yl)ethylidene]-hydrazide 、 nickel(II) acetate tetrahydrate 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 以62%的产率得到di([1-(furan-2-yl)ethylidene]-hydrazido)nickel(II)
  参考文献：
  名称：

  Synthesis, Magnetic, Thermal, and Spectral Studies of Some Chelates of Cu(II), Ni(II), Zn(II), Co(II), Mn(II), Sm(III), and Th(IV) Involving Aroylhydrazones Derived from Isonicotinic Acid Hydrazide and 2‐Furyl Methyl and 2‐Thienyl Methyl Ketone

  摘要：

  Two aroylhydrazones, viz., isonicotinic acid [1-(furan-2-yl)ethylidene]hydrazide (IFEH) and isonicotinic acid [1-(thiophene-2-yl)ethylidene]hydrazide (ITEH) have been synthesized by the interaction of 2-furyl methyl ketone and 2-thienyl methyl ketone with isonicotinic acid hydrazide in ethanol. Metal chelates of these hydrazones of the compositions [Cu(IFE)(2)(H2O)(2)].H2O (1), [Ni(IFE)(2)].H2O (2), [Co(IFE)(2)(H2O)(2)] (3), [Mn(IFE)(2)(H2O)(2)].H2O (4), [Zn(IFE)(2)]-H2O (5), [Cu(ITE)(2)] (6), [Zn(ITE)(2)] (7), [Sm(ITE)(2)(OAc)(H2O) (8) and [Th(ITE)(2) (NO3)(2)] (9) (HOAc = CH3COOH) have been prepared. The coordination behaviour of these two hydrazones with different metal ions has been discussed on the basis of analytical data, electronic spectra, magnetic measurements, thermogravimetric analyses, and infrared and nuclear magnetic resonance spectral studies.

  DOI：

  10.1081/sim-120026553