N-(2,6-diethylphenyl)-1-(2-trimethylsilyloxyphenyl)methanimine | 403507-95-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2,6-diethylphenyl)-1-(2-trimethylsilyloxyphenyl)methanimine
• CAS: 403507-95-9
• 化学式: C₂₀H₂₇NOSi
• 分子量: 325.526
• InChiKey: SBCGREVUJWJTGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.78
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  21.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(2,6-diethylphenyl)-1-(2-trimethylsilyloxyphenyl)methanimine 、 氯化锆(IV) 以 苯 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  SYNTHESIS, REACTIONS, AND SPECTRAL [NMR (¹H, ¹³C, ²⁹Si), IR] STUDIES OF TRIMETHYLSILYL-SUBSTITUTED N-ARYLSALICYLALDIMINATES

  摘要：

  Trimethylsilyl-substituted N-arylsalicylaidiminates Me3Si (OC6H4CH=NAr) [Ar=C6H5 (1), C6H3Me2-2,6 (2), C6H2Me3-2,4,6 (3), C3H3Et2-2,6 (4), and C6H3(Pr-i)(2)-2,6 (5)] have been prepared by the equimolar reactions of Me3SiCl with N-arylsalicylaldimines (LH) in benzene using Et3N as a base. Reactions in the desired molar ratios (1:1 or 2:1) of Me3Si(OC6H4CH=NAr) with TiCl4 and ZrCl4 afford a convenient and clean synthetic procedure for the preparation of chloride-salicylaldiminate derivatives of early transition metals. Characterisations of all these new derivatives have been carried out by elemental analyses, molecular weight determinations and spectroscopic [IR, NMR (H-1, C-13 and Si-29)] studies.

  DOI：

  10.1081/sim-100107714