Anthracen-2-carbonsaeurehydrazid | 2143-79-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: Anthracen-2-carbonsaeurehydrazid
• 英文别名: Anthracene-2-carboxylic acid hydrazide；anthracene-2-carbohydrazide
• CAS: 2143-79-5
• 化学式: C₁₅H₁₂N₂O
• 分子量: 236.273
• InChiKey: KFGVSBHBANUNNH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  55.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Anthracen-2-carbonsaeurehydrazid 在 PPA 作用下， 反应 4.0h， 以15%的产率得到2,5-Di(anthracen-2-yl)-1,3,4-oxadiazole
  参考文献：
  名称：

  Synthesis and Properties of Acene Dimers Linked by a 1,3,4-Oxadiazole Spacer

  摘要：

  Acene dimers linked by a 1,3,4-oxadiazole spacer were synthesized and their physical, optical, and electrochemical properties were investigated. The melting points and electron affinities of the dimers increased in the following order: benzene, naphthalene, and anthracene. The longest absorption maximum was red-shifted with an increase in the number of benzene rings. The Tc-conjugation between the two acene moieties through the oxadiazole spacer was not strong. Although no OFET properties were observed in a bottom contact device using the anthracene dimer as an active layer, the molecules were perpendicularly arranged on the substrate to form n-stacking films as observed in the X-Ray diffraction analysis.

  DOI：

  10.3987/com-06-s(k)4
• 作为产物：
  描述：

  甲基蒽-2-羧酸酯 在 一水合肼 作用下， 以 甲醇 为溶剂， 以88%的产率得到Anthracen-2-carbonsaeurehydrazid
  参考文献：
  名称：

  Synthesis and Properties of Acene Dimers Linked by a 1,3,4-Oxadiazole Spacer

  摘要：

  Acene dimers linked by a 1,3,4-oxadiazole spacer were synthesized and their physical, optical, and electrochemical properties were investigated. The melting points and electron affinities of the dimers increased in the following order: benzene, naphthalene, and anthracene. The longest absorption maximum was red-shifted with an increase in the number of benzene rings. The Tc-conjugation between the two acene moieties through the oxadiazole spacer was not strong. Although no OFET properties were observed in a bottom contact device using the anthracene dimer as an active layer, the molecules were perpendicularly arranged on the substrate to form n-stacking films as observed in the X-Ray diffraction analysis.

  DOI：

  10.3987/com-06-s(k)4

文献信息

• GOTO, JUNICHI;SAISHO, YUTAKA;NAMBARA, TOSHIO, ANAL. SCI., 5,(1989) N, C. 399-402
  作者：GOTO, JUNICHI、SAISHO, YUTAKA、NAMBARA, TOSHIO

  DOI：——

  日期：——